Impurity Sn-related paramagnetic defects in UV-illuminated ZnWO4single crystals
العنوان: | Impurity Sn-related paramagnetic defects in UV-illuminated ZnWO4single crystals |
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المؤلفون: | A. Watterich, O.R. Gilliam, L.A. Kappers |
المصدر: | Journal of Physics: Condensed Matter. 11:1333-1340 |
بيانات النشر: | IOP Publishing, 1999. |
سنة النشر: | 1999 |
مصطلحات موضوعية: | Chemistry, Condensed Matter Physics, Molecular physics, Symmetry (physics), law.invention, Paramagnetism, Nuclear magnetic resonance, Impurity, law, Condensed Matter::Strongly Correlated Electrons, General Materials Science, Spin density, Electron paramagnetic resonance, Ultraviolet radiation |
الوصف: | Electron spin resonance methods are used to characterize a new Sn-impurity-perturbed W5+ centre with C1 symmetry produced in ZnWO4 single crystals illuminated at 77 K with 365 nm UV light. The new centre is electron-like with its highest spin density at a W site, but also with a substantial spin density at an Sn impurity substituting for a neighbouring Zn cation. It is denoted as a W5+ - SnZn++ centre. The concentration of this defect is estimated to be less than 1 µmol mol-1. |
تدمد: | 1361-648X 0953-8984 |
DOI: | 10.1088/0953-8984/11/5/018 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::7130f2e9905ba718e5b54635375d2b58 https://doi.org/10.1088/0953-8984/11/5/018 |
رقم الانضمام: | edsair.doi...........7130f2e9905ba718e5b54635375d2b58 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 1361648X 09538984 |
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DOI: | 10.1088/0953-8984/11/5/018 |