Complexes [Ni2(μ-OH2)(μ-O2CCH(CH3)2)2L2–4((CH3)2CHCO2)2]: Synthesis, Structure, and Mass Spectrometric Studies
| العنوان: | Complexes [Ni2(μ-OH2)(μ-O2CCH(CH3)2)2L2–4((CH3)2CHCO2)2]: Synthesis, Structure, and Mass Spectrometric Studies |
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| المؤلفون: | Vladislav V. Gurzhiy, Alexei V. Eremin, N. S. Panina, A. E. Minkovich, A. N. Belyaev, M. Yu. Maksimov, D. O. Blinou, A. A. Nikiforov |
| المصدر: | Russian Journal of Coordination Chemistry. 46:81-88 |
| بيانات النشر: | Pleiades Publishing Ltd, 2020. |
| سنة النشر: | 2020 |
| مصطلحات موضوعية: | chemistry.chemical_classification, General Chemical Engineering, chemistry.chemical_element, General Chemistry, Tetramethylethylenediamine, 010402 general chemistry, 010403 inorganic & nuclear chemistry, Mass spectrometry, 01 natural sciences, Medicinal chemistry, 0104 chemical sciences, Coordination complex, chemistry.chemical_compound, Nickel, chemistry, Pyridine, Mass spectrum, Spectroscopy, Acetonitrile |
| الوصف: | Three new binuclear aqua-bridged nickel(II) 2-methylpropionate complexes [Ni2(μ-OH2)(μ-O2CCH(CH3)2)2L2–4((CH3)2CHCO2)2] (L is N,N,N',N'-tetramethylethylenediamine (I), pyridine (II), and 2,2'-bipyridyl (III)) are synthesized. The complexes are characterized by elemental and thermal analyses, mass spectrometry, IR and UV–Vis spectroscopy, and X-ray structure analysis (CIF files CCDC nos. 1840763 (I), 1913469 (II), and 1913471 (III)). The forms in which the synthesized coordination compounds exist in acetonitrile solutions are proposed on the basis of analyzing their mass spectra. |
| تدمد: | 1608-3318 1070-3284 |
| DOI: | 10.1134/s1070328420020037 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::6741a350c3e8a25ab48018352507c2eb https://doi.org/10.1134/s1070328420020037 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi...........6741a350c3e8a25ab48018352507c2eb |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 16083318 10703284 |
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| DOI: | 10.1134/s1070328420020037 |