The polarized emission behaviors of the Eu 3+ doped azo-polymer waveguide were reported in this paper. Affected by the azobenzene groups in the photoinduced orientation process by the 532nm linearly polarized laser, the ligands were realigned orderly perpendicular to the direction of the orientation direction. This leads to the polarized absorption and emission of the waveguide in the orientation direction. By an m-line apparatus based on the prism coupling technique, two guided modes propagation were observed in the waveguide at 650nm in TE polarizations.