New Oxazaborolidine Catalysts for the Diels–Alder Reaction
| العنوان: | New Oxazaborolidine Catalysts for the Diels–Alder Reaction |
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| المؤلفون: | Hisashi Yamamoto, Yasushi Shimoda |
| المصدر: | Synthesis. 49:175-180 |
| بيانات النشر: | Georg Thieme Verlag KG, 2016. |
| سنة النشر: | 2016 |
| مصطلحات موضوعية: | chemistry.chemical_compound, Chemistry, Organic Chemistry, Enantioselective synthesis, Organic chemistry, Alcohol, Lewis acids and bases, Catalysis, Boronic acid, Diels–Alder reaction, Adduct |
| الوصف: | A new axially chiral oxazaborolidine catalyst has been developed. This catalyst consists of a chiral boronic acid and an easily modifiable achiral amino alcohol. It could be applied to a Diels–Alder reaction to give the corresponding adduct with good enantioselectivity. Additionally, the bis(oxazaborolidine) catalyst, bearing two Lewis acidic centers enabled a Diels–Alder reaction with higher enantioselectivity. |
| تدمد: | 1437-210X 0039-7881 |
| DOI: | 10.1055/s-0036-1588082 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::5fa8d97e956f8bfd7728b8c94d39cb04 https://doi.org/10.1055/s-0036-1588082 |
| رقم الانضمام: | edsair.doi...........5fa8d97e956f8bfd7728b8c94d39cb04 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1437210X 00397881 |
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| DOI: | 10.1055/s-0036-1588082 |