Degradation of Bisphenol A by Peroxymonosulfate Catalytically Activated with Mn1.8Fe1.2O4 Nanospheres: Synergism between Mn and Fe
| العنوان: | Degradation of Bisphenol A by Peroxymonosulfate Catalytically Activated with Mn1.8Fe1.2O4 Nanospheres: Synergism between Mn and Fe |
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| المؤلفون: | Han-Qing Yu, Gui-Xiang Huang, Chuan-Wang Yang, Pu-Can Guo, Chu-Ya Wang |
| المصدر: | Environmental Science & Technology. 51:12611-12618 |
| بيانات النشر: | American Chemical Society (ACS), 2017. |
| سنة النشر: | 2017 |
| مصطلحات موضوعية: | Bisphenol A, biology, Chemistry, Inorganic chemistry, Active site, 02 engineering and technology, General Chemistry, 010501 environmental sciences, 021001 nanoscience & nanotechnology, 01 natural sciences, Catalysis, Metal, chemistry.chemical_compound, Adsorption, visual_art, biology.protein, visual_art.visual_art_medium, Environmental Chemistry, Degradation (geology), Phenols, 0210 nano-technology, Bimetallic strip, 0105 earth and related environmental sciences |
| الوصف: | A high-efficient, low-cost, and eco-friendly catalyst is highly desired to activate peroxides for environmental remediation. Due to the potential synergistic effect between bimetallic oxides’ two different metal cations, these oxides exhibit superior performance in the catalytic activation of peroxymonosulfate (PMS). In this work, novel Mn1.8Fe1.2O4 nanospheres were synthesized and used to activate PMS for the degradation of bisphenol A (BPA), a typical refractory pollutant. The catalytic performance of the Mn1.8Fe1.2O4 nanospheres was substantially greater than that of the Mn/Fe monometallic oxides and remained efficient in a wide pH range from 4 to 10. More importantly, a synergistic effect between solid-state Mn and Fe was identified in control experiments with Mn3O4 and Fe3O4. Mn was inferred to be the primary active site in the surface of the Mn1.8Fe1.2O4 nanospheres, while Fe(III) was found to play a key role in the synergism with Mn by acting as the main adsorption site for the reaction substrates.... |
| تدمد: | 1520-5851 0013-936X |
| DOI: | 10.1021/acs.est.7b03007 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::58c870b8ceb759c841681eee162a3d7e https://doi.org/10.1021/acs.est.7b03007 |
| رقم الانضمام: | edsair.doi...........58c870b8ceb759c841681eee162a3d7e |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15205851 0013936X |
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| DOI: | 10.1021/acs.est.7b03007 |