FISSION OF AS-AS BONDS IN ELEMENTAL ARSENIC BY ALKALI METALS IN LIQUID AMMONIA. A ROUTE TO MONOALKYL ARSINES
| العنوان: | FISSION OF AS-AS BONDS IN ELEMENTAL ARSENIC BY ALKALI METALS IN LIQUID AMMONIA. A ROUTE TO MONOALKYL ARSINES |
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| المؤلفون: | O. Bj⊘rlo, H. W. A. Biessels, J. Schuring, Lambert Brandsma, H. D. Verkruijsse, A. C. van der Kerk‐Van Hoof |
| المصدر: | Phosphorus, Sulfur, and Silicon and the Related Elements. 166:261-264 |
| بيانات النشر: | Informa UK Limited, 2000. |
| سنة النشر: | 2000 |
| مصطلحات موضوعية: | chemistry.chemical_classification, Organic Chemistry, Iodide, Inorganic chemistry, technology, industry, and agriculture, chemistry.chemical_element, Alcohol, Alkali metal, Biochemistry, Arsenide, Inorganic Chemistry, chemistry.chemical_compound, Arsine, chemistry, Yield (chemistry), lipids (amino acids, peptides, and proteins), Lithium, Arsenic |
| الوصف: | Addition of two mol equivalents of t-butyl alcohol to a mixture of powdered arsenic and three mol equivalents of lithium in liquid ammonia gives a suspension of lithium arsenide LiAsH2. Subsequent addition of a large excess of t-butyl alcohol and n-octyl iodide at very low temperatures affords n-octyl arsine in -65% yield. |
| تدمد: | 1563-5325 1042-6507 |
| DOI: | 10.1080/10426500008076547 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::5853d85b63cfa5ed70c9a04d0486a9fb https://doi.org/10.1080/10426500008076547 |
| رقم الانضمام: | edsair.doi...........5853d85b63cfa5ed70c9a04d0486a9fb |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15635325 10426507 |
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| DOI: | 10.1080/10426500008076547 |