Hydrodemetallation of a vanadylporphyrin over sulfided NiMoγAl2O3, MoγAl2O3, and γAl2O3 catalysts - effect of the vanadium deposit on the toluene hydrogenation
التفاصيل البيبلوغرافية
العنوان:
Hydrodemetallation of a vanadylporphyrin over sulfided NiMoγAl2O3, MoγAl2O3, and γAl2O3 catalysts - effect of the vanadium deposit on the toluene hydrogenation
The toluene hydrogenation performances of Mo and NiMoAl2O3 hydrotreating catalysts are modified by vanadium deposited through HDM of the Vanadylporphyrin. Bulk deposited vanadium sulfide of mean VS1.1 stoichiometry does not greatly affect the intrinsic performances of the initial catalysts but it appears that a part of the deposited vanadium replaces Ni in the NiMoS phase and acts as a promoter of the supported MoS2