Silyl–pyridine–amine pincer-ligated iridium complexes for catalytic silane deuteration via room temperature C–D bond activation of benzene-d6
| العنوان: | Silyl–pyridine–amine pincer-ligated iridium complexes for catalytic silane deuteration via room temperature C–D bond activation of benzene-d6 |
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| المؤلفون: | Daiki Mochizuki, Tomohiro Osawa, Hiromi Tobita, Takashi Komuro, Ryuju Suzuki, Hironori Higashi |
| المصدر: | Chemical Communications. 55:957-960 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2019. |
| سنة النشر: | 2019 |
| مصطلحات موضوعية: | Silylation, 010405 organic chemistry, Metals and Alloys, chemistry.chemical_element, General Chemistry, 010402 general chemistry, 01 natural sciences, Silane, Catalysis, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Pincer movement, chemistry.chemical_compound, chemistry, Pyridine, Polymer chemistry, Materials Chemistry, Ceramics and Composites, Amine gas treating, Iridium, Pincer ligand |
| الوصف: | Iridium-hydrido complexes bearing a hemilabile silyl-pyridine-amine pincer ligand were synthesised. They were found to catalyse Si-H deuteration of trialkylsilanes with excess benzene-d6 in 99-94% conversion at room temperature through C-D bond activation and H/D exchange. |
| تدمد: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c8cc09178a |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::43a4d0778f8f09e63f0f278e45064ab1 https://doi.org/10.1039/c8cc09178a |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi...........43a4d0778f8f09e63f0f278e45064ab1 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1364548X 13597345 |
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| DOI: | 10.1039/c8cc09178a |