Surface and lightning sources of nitrogen oxides over the United States: Magnitudes, chemical evolution, and outflow

التفاصيل البيبلوغرافية
العنوان: Surface and lightning sources of nitrogen oxides over the United States: Magnitudes, chemical evolution, and outflow
المؤلفون: Eric M. Leibensperger, Daniel J. Jacob, Aaron L. Swanson, Ronald C. Cohen, J. A. Neuman, Shiliang Wu, Solène Turquety, Timothy H. Bertram, Anne E. Perring, Melody A. Avery, Frank Flocke, Jack E. Dibb, Lee T. Murray, Richard E. Orville, Hanwant B. Singh, Paul J. Wooldridge, Alice B. Gilliland, R. C. Hudman, Alan Fried, William H. Brune, G. W. Sachse, J. S. Holloway, Xinrong Ren
المصدر: Journal of Geophysical Research. 112
بيانات النشر: American Geophysical Union (AGU), 2007.
سنة النشر: 2007
مصطلحات موضوعية: Atmospheric Science, Ozone, Ecology, Reactive nitrogen, Paleontology, Soil Science, Forestry, Aquatic Science, Oceanography, Lightning, Troposphere, chemistry.chemical_compound, Geophysics, chemistry, Space and Planetary Science, Geochemistry and Petrology, Climatology, Atmospheric chemistry, Earth and Planetary Sciences (miscellaneous), Environmental science, Outflow, Nitrogen oxide, Tropospheric ozone, Earth-Surface Processes, Water Science and Technology
الوصف: We use observations from two aircraft during the International Consortium for Atmospheric Research on Transport and Transformation (ICARTT) campaign over the eastern United States and North Atlantic during summer 2004, interpreted with a global 3-D model of tropospheric chemistry (GEOS-Chem) to test current understanding of the regional sources, chemical evolution, and export of nitrogen oxides. The boundary layer NO(x) data provide top-down verification of a 50% decrease in power plant and industry NO(x) emissions over the eastern United States between 1999 and 2004. Observed 8-12 8 km NO(x) concentrations in ICARTT were 0.55 +/- 36 ppbv, much larger than in previous United States aircraft campaigns (ELCHEM, SUCCESS, SONEX). We show that regional lightning was the dominant source of this NO(x) and increased upper tropospheric ozone by 10 ppbv. Simulating the ICARTT upper tropospheric NO(x) observations with GEOS-Chem require a factor of 4 increase in the model NO(x) yield per flash (to 500 mol/flash). Observed OH concentrations were a factor of 2 lower than can be explained from current photochemical models, and if correct would imply a broader lightning influence in the upper troposphere than presently thought.An NO(y)-CO correlation analysis of the fraction f of North American NO(x) emissions vented to the free troposphere as NO(y) (sum of NO(x) and its oxidation products PAN and HNO3) s shows observed f=16+/-10 percent and modeled f=14 +/- 8 percent, consistent with previous studies. Export to the lower free troposphere is mostly HNO3 but at higher altitudes is mostly PAN. The model successfully simulates NO(y) export efficiency and speciation, supporting previous model estimates of a large U.S. contribution to tropospheric ozone through NO(x) and PAN export.
تدمد: 0148-0227
DOI: 10.1029/2006jd007912
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::407d74dff9f272399f3f2a799e766487
https://doi.org/10.1029/2006jd007912
Rights: OPEN
رقم الانضمام: edsair.doi...........407d74dff9f272399f3f2a799e766487
قاعدة البيانات: OpenAIRE
الوصف
تدمد:01480227
DOI:10.1029/2006jd007912