Potential Constants and Thermodynamic Functions of Iodine Pentafluoride

التفاصيل البيبلوغرافية
العنوان: Potential Constants and Thermodynamic Functions of Iodine Pentafluoride
المؤلفون: G. Nagarajan
المصدر: Bulletin des Sociétés Chimiques Belges. 72:5-15
بيانات النشر: Wiley, 2010.
سنة النشر: 2010
مصطلحات موضوعية: Chemistry, Thermodynamics, General Chemistry, Kinetic energy, Heat capacity, symbols.namesake, Tetragonal crystal system, chemistry.chemical_compound, Central force, Iodine pentafluoride, symbols, Physical chemistry, Rigid rotor, Raman spectroscopy, Harmonic oscillator
الوصف: An orthonormalized set of symmetry coordinates satisfying the transformation properties has been constructed for the iodine pentafluoride molecule having the tetragonal pyramidal structure with the symmetry point group C4v. Utilizing these symmetry coordinates and a potential function consisting of the ordinary valance force terms and central force terms, the elements of potential and kinetic energy matrices have been obtained. From the observed Raman and infrared fundamental frequencies the potential constants and thermodynamic functions such as heat content, free energy, entropy and heat capacity have been calculated for a rigid rotator, harmonic oscillator approximation.
تدمد: 0037-9646
DOI: 10.1002/bscb.19630720101
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::3b0a5ab95402c8e4c320017143850610
https://doi.org/10.1002/bscb.19630720101
Rights: CLOSED
رقم الانضمام: edsair.doi...........3b0a5ab95402c8e4c320017143850610
قاعدة البيانات: OpenAIRE
الوصف
تدمد:00379646
DOI:10.1002/bscb.19630720101