Preparation and characterization of methyl 11-amino-(N-p-toluenesulfonyl)-9-E-octadecenoate and methyl 8-amino-(N-p-toluenesulfonyl)-9-E-octadecenoate

التفاصيل البيبلوغرافية
العنوان: Preparation and characterization of methyl 11-amino-(N-p-toluenesulfonyl)-9-E-octadecenoate and methyl 8-amino-(N-p-toluenesulfonyl)-9-E-octadecenoate
المؤلفون: David Weisleder, Terry A. Isbell, W C Byrdwell, Ron Plattner, Marvin O. Bagby, Barry F. Herron
المصدر: Journal of the American Oil Chemists' Society. 74:229-234
بيانات النشر: Wiley, 1997.
سنة النشر: 1997
مصطلحات موضوعية: Allylic rearrangement, Chemistry, Stereochemistry, General Chemical Engineering, Yield (chemistry), Organic Chemistry, Infrared spectroscopy, Mass spectrometry, Aliphatic compound, Chemical synthesis, Amination, Unsaturated fatty acid
الوصف: Allylic amination of methyl oleate with bis(N-p-toluenesulfonyl) sulfodiimide results in a mixture of methyl 11-amino-(N-p-toluenesulfonyl)-9-E-octadecenoate and methyl 8-amino-(N-p-toluenesulfonyl)-9-E-octadecenoate in 58% yield. These novel products were isolated and characterized by nuclear magnetic resonance, infrared spectroscopy, mass spectrometry, and melting point. The reaction was analyzed by highperformance liquid chromatography and thin-layer chromatography.
تدمد: 0003-021X
DOI: 10.1007/s11746-997-0128-7
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::1dd99c953e74586dc643fba489a2ef95
https://doi.org/10.1007/s11746-997-0128-7
Rights: CLOSED
رقم الانضمام: edsair.doi...........1dd99c953e74586dc643fba489a2ef95
قاعدة البيانات: OpenAIRE
الوصف
تدمد:0003021X
DOI:10.1007/s11746-997-0128-7