Supramolecular Assembling through Anionic Iodine Secondary Bonds: Synthesis and X-ray Characterization of (Et4N)[PhTeI4] and (Et4N)[(β-Naphthyl)TeI4]
| العنوان: | Supramolecular Assembling through Anionic Iodine Secondary Bonds: Synthesis and X-ray Characterization of (Et4N)[PhTeI4] and (Et4N)[(β-Naphthyl)TeI4] |
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| المؤلفون: | Gabriela N. Ledesma, Gelson Manzoni de Oliveira, Ernesto Schulz Lang |
| المصدر: | Zeitschrift für anorganische und allgemeine Chemie. 631:1524-1527 |
| بيانات النشر: | Wiley, 2005. |
| سنة النشر: | 2005 |
| مصطلحات موضوعية: | Inorganic Chemistry, Crystallography, Tetraethylammonium iodide, chemistry.chemical_compound, Octahedron, Hydrogen bond, Stereochemistry, Chemistry, Supramolecular chemistry, Ionic bonding, Protonation, Square pyramidal molecular geometry, Monoclinic crystal system |
| الوصف: | [PhTe]2 and [(β-naphthyl)Te]2 react with iodine and tetraethylammonium iodide in toluene/methanol to give (Et4N)[PhTeI4] and (Et4N)[(β-Naphthyl)TeI4]. The complexes were analysed by single crystal X-ray diffraction affording the centrosymmetric monoclinic space group P21/c. In the novel compounds only anionic interactions of the types Te···I and I···I take place, cation-anion effective contacts do not occur. Both anions [PhTeI4] and [(β-naphthyl)TeI4] exhibit square pyramidal coordination at tellurium, with the iodine atoms in the basal positions and the organic groups apical. The tellurium centers achieve an octahedral coordination in the whole lattices through Te···I secondary bonds with the adjacent ionic species. Only the Te–I- and I–I-secondary bonds behave as structure-forming interactions in the self-organization of the supramolecular anionic gatherings. New evidences show that for organyltellurates (Q)[PhTeX4] (Q = protonated amines, amides or amino acids; X = Cl, Br, I), NH···X hydrogen bondings are able to hinder the anionic halogen-halogen secondary interactions. In case of the more frequent I···I interactions, they have been observed only in the absence of NH···I hydrogen bonds. |
| تدمد: | 1521-3749 0044-2313 |
| DOI: | 10.1002/zaac.200500033 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::155cd0023e24cb273a5e5f2afd1e6206 https://doi.org/10.1002/zaac.200500033 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi...........155cd0023e24cb273a5e5f2afd1e6206 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15213749 00442313 |
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| DOI: | 10.1002/zaac.200500033 |