A Versatile Route toN,N′-(Peraryl)substituted 5,5′-Diamino-2,2′-bithiophenes
العنوان: | A Versatile Route toN,N′-(Peraryl)substituted 5,5′-Diamino-2,2′-bithiophenes |
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المؤلفون: | Horst Hartmann, Dirk Rohde, Peter Gerstner |
المصدر: | Synthesis. :2487-2489 |
بيانات النشر: | Georg Thieme Verlag KG, 2002. |
سنة النشر: | 2002 |
مصطلحات موضوعية: | Tris, Organic Chemistry, chemistry.chemical_element, Medicinal chemistry, Catalysis, Amorphous solid, chemistry.chemical_compound, chemistry, Tetrachloride, Nucleophilic substitution, Phosphine, Palladium, A titanium |
الوصف: | The reaction of 5,5'-dibromo-2,2'-bithiophene with diarylamines in the presence of palladium acetate/tris-(t-butyl)phosphine as catalyst or by a titanium tetrachloride mediated oxidation of 2-(N,N-diarylamino)thiophenes has yielded a series of new N,N'-perarylated 5,5-diamino-2,2'-hithiophenes. These are electron-rich compounds with a low oxidation potential and have a high tendency to form amorphous glasses. |
تدمد: | 1437-210X 0039-7881 |
DOI: | 10.1055/s-2002-35620 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::08636a0bea21516cb9f3c4b5510adea2 https://doi.org/10.1055/s-2002-35620 |
رقم الانضمام: | edsair.doi...........08636a0bea21516cb9f3c4b5510adea2 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 1437210X 00397881 |
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DOI: | 10.1055/s-2002-35620 |