Replacement of Ligands in a Molecule of Polyhedral Phenylmetallosiloxane Containing Nickel and Sodium Ions
| العنوان: | Replacement of Ligands in a Molecule of Polyhedral Phenylmetallosiloxane Containing Nickel and Sodium Ions |
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| المؤلفون: | Anton Anisimov, Yu. S. Vysochinskaya, Olga I. Shchegolikhina, P. V. Zhemchugov, Aziz M. Muzafarov, Fedor M. Dolgushin |
| المصدر: | Russian Journal of Coordination Chemistry. 44:653-659 |
| بيانات النشر: | Pleiades Publishing Ltd, 2018. |
| سنة النشر: | 2018 |
| مصطلحات موضوعية: | 010405 organic chemistry, Chemistry, General Chemical Engineering, Sodium, Cationic polymerization, chemistry.chemical_element, General Chemistry, 010402 general chemistry, 01 natural sciences, 0104 chemical sciences, Ion, Crystallography, Nickel, Molecule |
| الوصف: | The possibility of the partial or complete substitution of the outer-sphere solvate shell of n-butanol molecules by the nitrogen-containing compounds in the phenylnickelsodiumsiloxane complex. The high-symmetry spatially fixed rigidly cationic layer retains its structure. The obtained complexes Na2(μ-H2O)2(n-BuOH)2{[C6H5SiO2]6Ni4Na4(μ3-OH)2[C6H5SiO2]6} · 8(n-BuOH) · 2NH3 (II) and {[C6H5SiO2]6Ni4Na6(μ3-OH)2[C6H5SiO2]6} · 4(μ-C3H7NO) · 6(C3H7NO) · 2.8(H2O) · 0.6(C3H7NO) (III) are studied by X-ray diffraction analysis (CIF files CCDC nos. 1810736 (II) and 1810737 (III)). |
| تدمد: | 1608-3318 1070-3284 |
| DOI: | 10.1134/s1070328418110088 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::02b72e83d71e0cff40e537d94532c180 https://doi.org/10.1134/s1070328418110088 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi...........02b72e83d71e0cff40e537d94532c180 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 16083318 10703284 |
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| DOI: | 10.1134/s1070328418110088 |