Generation of Cobalt-Containing Nanoparticles on Carbon via Pyrolysis of a Cobalt Corrole and Its Application in the Hydrogenation of Nitroarenes

التفاصيل البيبلوغرافية
العنوان: Generation of Cobalt-Containing Nanoparticles on Carbon via Pyrolysis of a Cobalt Corrole and Its Application in the Hydrogenation of Nitroarenes
المؤلفون: Jessica Michalke, Michael Haas, Dominik Krisch, Thomas Bögl, Stephan Bartling, Nils Rockstroh, Wolfgang Schöfberger, Christoph Topf
المصدر: Catalysts, Vol 12, Iss 11, p 11 (2022)
بيانات النشر: MDPI AG, 2022.
سنة النشر: 2022
مصطلحات موضوعية: Chemistry, corrole, heterogeneous hydrogenation, Chemical technology, TP1-1185, pyrolysis, cobalt, QD1-999, base metal catalysis
الوصف: We report on the manufacture of a state-of-the-art heterogeneous non-noble metal catalyst, which is based on a molecularly well-defined phosphine-tagged cobalt corrole complex. This precursor compound is readily synthesized from convenient starting materials while the active material is obtained through wet-impregnation of the pertinent metalliferous macrocycle onto carbon black followed by controlled pyrolysis of the loaded carrier material under an inert gas atmosphere. Thus, the obtained composite was then applied in the heterogeneous hydrogenation of various nitroarenes to yield a vast array of valuable aniline derivatives that were conveniently isolated as their hydrochloride salts. The introduced catalytic protocol is robust and user-friendly with the entire assembly of the reaction set-up enabling the conduction of the experiments on the laboratory bench without any protection from air.
اللغة: English
تدمد: 2073-4344
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doajarticles::1a884fe3052ebb220c0122a96fef72c7
https://www.mdpi.com/2073-4344/12/1/11
Rights: OPEN
رقم الانضمام: edsair.doajarticles..1a884fe3052ebb220c0122a96fef72c7
قاعدة البيانات: OpenAIRE