Periodical
Chemoenzymatic one-pot reaction from carboxylic acid to nitrile viaoximeElectronic supplementary information (ESI) available. See DOI: 10.1039/d1cy01694f
| العنوان: | Chemoenzymatic one-pot reaction from carboxylic acid to nitrile viaoximeElectronic supplementary information (ESI) available. See DOI: 10.1039/d1cy01694f |
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| المؤلفون: | Horvat, Melissa, Weilch, Victoria, Rädisch, Robert, Hecko, Sebastian, Schiefer, Astrid, Rudroff, Florian, Wilding, Birgit, Klempier, Norbert, Pátek, Miroslav, Martínková, Ludmila, Winkler, Margit |
| المصدر: | Catalysis Science & Technology; 2022, Vol. 12 Issue: 1 p62-66, 5p |
| مستخلص: | We report a new chemoenzymatic cascade starting with aldehyde synthesis by carboxylic acid reductase (CAR) followed by chemical in situoxime formation. The final step to the nitrile is catalyzed by aldoxime dehydratase (Oxd). Full conversions of phenylacetic acid and hexanoic acid were achieved in a two-phase mode. |
| قاعدة البيانات: | Supplemental Index |
| تدمد: | 20444753 20444761 |
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| DOI: | 10.1039/d1cy01694f |