Synthesis of Hole-Transporting Materials Containing Triarylamine and its Properties

التفاصيل البيبلوغرافية
العنوان: Synthesis of Hole-Transporting Materials Containing Triarylamine and its Properties
المؤلفون: Gao, Wen Zheng, Li, Xiang Gao, Wang, Shi Rong
المصدر: Applied Mechanics and Materials; March 2012, Vol. 161 Issue: 1 p121-127, 7p
مستخلص: Two hole-transporting materials containing triphenylamine unit, 4-(4-(di-p- tolylamino)styryl)-N,N-di-p-tolylbenzenamine (TM 1) and 4-(4-(4-(di-p-tolylamino)styryl) styryl)-N,N-di-p-tolylbenzenamine(TM 2), have been designed and synthesized in this paper, which using conjugated bonds as the bridge to connect two molecules of triphenylamine. The optical spectrum, thermo-stabilization and electrochemical properties of two compounds were studied. The results show that these compounds have blue emission, proper HOMO levels and high thermal stability. Furthermore, EL devices with the configuration of ITO/HTL/Alq3/Al show the activating voltages are 11V for TM 1 and 5.5V for TM 2, respectively. The maximal luminancce efficiencies are 1.135cd/A for TM 1 and 2.068cd/A for TM 2, respectively. The difference of EL performance indicates that TM 2 possessing better hole-transporting performance than that of TM 1.
قاعدة البيانات: Supplemental Index
الوصف
تدمد:16609336
16627482
DOI:10.4028/www.scientific.net/AMM.161.121