Periodical
Electroactive Organic-Inorganic Layered Perovskite Hybrids: Steric Interaction between Aminopyridine and Trivalent Ferricyanide and Use for Electrochemical Sensing Device
| العنوان: | Electroactive Organic-Inorganic Layered Perovskite Hybrids: Steric Interaction between Aminopyridine and Trivalent Ferricyanide and Use for Electrochemical Sensing Device |
|---|---|
| المؤلفون: | Wu, Jing, Liu, Han Xing, Lin, Zhi Dong, Cao, Ming He, Guo, Li Lin, Hao, Hua, Yu, Zhi Yong |
| المصدر: | Materials Science Forum; March 2011, Vol. 682 Issue: 1 p239-249, 11p |
| مستخلص: | Steady organic-inorganic perovskite hybrids with (H22-Ap)3/2Fe(CN)6, (H23-Ap)3/2Fe(CN)6 and (H24-AP)3/2Fe(CN)6 (2-AP = 2-aminopyridine, 3-AP = 3- aminopyridine, 4-AP = 4- aminopyridine) were formed from aqueous solution. Each structure was an unusual layered organic-inorganic structural type. A device was designed to construct electrochemical sensing devices using above organic-inorganic perovskite hybrids. The sequence of redox activity is (H24-Ap)3/2Fe(CN)6 > (H22-Ap)3/2Fe(CN)6 > (H23-AP)3/2Fe(CN)6 and that of electrocatalytical activity is (H22-Ap)3/2Fe(CN)6 > (H23-Ap)3/2Fe(CN)6 > (H24-AP)3/2Fe(CN)6. The variation coefficients (RSD) of successive and interval assays are less than 2.0%. Three electrochemical sensing devices display a remarkable electrochemical sensitivity and stability. |
| قاعدة البيانات: | Supplemental Index |
| تدمد: | 02555476 16629752 |
|---|---|
| DOI: | 10.4028/www.scientific.net/MSF.682.239 |