التفاصيل البيبلوغرافية
| العنوان: |
A Facile Route for Stabilizing Highly Reactive ArTeCl Species Through the Formation of T-Shaped Tellurenyl Chloride Adducts: quasi-Planar Zwitterionic [HPy*]TeCl2 and [HPm*]TeCl2; Py* = 2-pyridyl, Pm* = 2-(4,6-dimethyl)pyrimidyl. |
| المؤلفون: |
Khrustalev, Victor N., Matsulevich, Zhanna V., Lukiyanova, Julia M., Aysin, Rinat R., Peregudov, Alexander S., Leites, Larissa A., Borisov, Alexander V. |
| المصدر: |
European Journal of Inorganic Chemistry; Aug2014, Vol. 2014 Issue 22, p3582-3586, 5p |
| مصطلحات موضوعية: |
TELLURIUM compounds synthesis, CHEMICAL adducts, ZWITTERIONS, INFRARED spectroscopy, RAMAN spectroscopy, X-ray diffraction |
| مستخلص: |
Two new stable T-shaped tellurenyl chloride adducts, viz., [HPy*]TeCl2 ( 1) and [HPm*]TeCl2 ( 2) [Py* = 2-pyridyl, Pm* = 2-(4,6-dimethyl)pyrimidyl], act as close chemical analogs of highly unstable monomeric Py*TeCl and Pm*TeCl. The quasi-planar zwitterionic structures of 1 and 2 have been studied by experimental (X-ray diffraction, multinuclear NMR, IR and Raman spectroscopy) and theoretical (DFT and QTAIM) methods. Thus, a novel facile route to stabilize highly reactive Ar*TeCl species (Ar* = N-functionalized aryl) by the addition of a hydrochloric acid molecule has been demonstrated. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |