Academic Journal

Mechanism of electrochemical oxidation of spatially hindered amines of 2,2,6,6-tetramethylpiperidine series.

التفاصيل البيبلوغرافية
العنوان: Mechanism of electrochemical oxidation of spatially hindered amines of 2,2,6,6-tetramethylpiperidine series.
المؤلفون: Kagan, E., Zhukova, I., Yanilkin, V., Morozov, V., Nastapova, N., Kashparova, V., Kashparov, I.
المصدر: Russian Journal of Electrochemistry; Nov2011, Vol. 47 Issue 11, p1199-1204, 6p
مصطلحات موضوعية: ELECTROCHEMICAL analysis, ELECTRON paramagnetic resonance spectroscopy, ACETONITRILE, VOLTAMMETRY, SPECTRUM analysis, CATIONS, RADICALS, AMINYL radicals
مستخلص: Electrooxidation of spatially hindered amines of the series of 2,2,6,6-tetramethylpiperidine in the medium of acetonitrile results in formation of radical cations, aminyl radicals, nitroxyl radicals, and oxoammonium salts identified using the methods of cyclic voltammetry and ESR spectroscopy. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:10231935
DOI:10.1134/S1023193511110073