التفاصيل البيبلوغرافية
| العنوان: |
An efficient heteropolyacid catalyzed acylation of pyruvate esters to α-acyloxyacrylate esters as potential candidate monomers for bio-based polymers. |
| المؤلفون: |
Wataru Ninomiya, Masahiro Sadakane, Shinji Matsuoka, Hiroki Nakamura, Hiroyuki Naitou, Wataru Ueda |
| المصدر: |
Chemical Communications; Oct2008, Vol. 2008 Issue 41, p5239-5241, 3p |
| مصطلحات موضوعية: |
ESTERS, ORGANIC compounds, PYRUVATES, CHEMICAL inhibitors |
| مستخلص: |
α-Acyloxyacrylate esters were efficiently synthesized from pyruvate esters and carboxylic anhydrides under mild conditions. These esters are potential candidate monomers for bio-based polymers with high durability and transparency. Tungsten-based Keggin type heteropolyacids, especially H3PW12O40, worked more effectively as catalysts for this reaction than other typical acids. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |