التفاصيل البيبلوغرافية
| العنوان: |
Cycloadditions of Diazoalkenes with P4 and tBuCP: Access to Diazaphospholes. |
| المؤلفون: |
Hauer, Sebastian, Reitz, Justus, Koike, Taichi, Hansmann, Max M., Wolf, Robert |
| المصدر: |
Angewandte Chemie International Edition; 9/16/2024, Vol. 63 Issue 38, p1-6, 6p |
| مصطلحات موضوعية: |
COORDINATION compounds, TRANSITION metal compounds, PHOSPHOLES, ELECTRONIC structure, ENDANGERED species |
| مستخلص: |
Diazoalkenes readily react with tert‐butylphosphaalkyne (tBuCP) and white phosphorus (P4) to afford novel phosphorus heterocycles, 3H‐1,2,4‐diazamonophospholes and 1,2,3,4‐diazadiphospholes. Both species represent rare examples of neutral heterophospholes. The mechanism of formation and the electronic structures of these formal (3+2) cycloaddition products were analyzed computationally. The new phospholes form structurally diverse coordination compounds with transition metal and main group elements. Given the growing number of stable diazoalkenes, this work offers a straightforward route to neutral aza(di‐)phospholes as a new ligand class. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |