التفاصيل البيبلوغرافية
| العنوان: |
Tuning a robust system: N,O zinc guanidine catalysts for the ROP of lactide. |
| المؤلفون: |
Schäfer, Pascal M., McKeown, Paul, Fuchs, Martin, Rittinghaus, Ruth D., Hermann, Alina, Henkel, Johanna, Seidel, Sebastian, Roitzheim, Christoph, Ksiazkiewicz, Agnieszka N., Hoffmann, Alexander, Pich, Andrij, Jones, Matthew D., Herres-Pawlis, Sonja |
| المصدر: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 5/14/2019, Vol. 48 Issue 18, p6071-6082, 12p |
| مصطلحات موضوعية: |
ZINC catalysts, GUANIDINES, MOLECULAR weights, POLYMERIZATION, POLYLACTIC acid, MONOMERS |
| مستخلص: |
Non-toxic, highly active and robust complexes are the holy grail as ideal green catalysts for the polymerisation of biorenewable and biodegradable polylactide. Four new zinc guanidine complexes [ZnCl2(TMG4NMe2asme)], [ZnCl2(TMG5Clasme)], [ZnCl2(TMG5Measme)] and [ZnCl2(TMG5NMe2asme)] with different electron-donating and electron-withdrawing groups on the ligand's aromatic backbone have been synthesised. Ligands are derived from low-cost commercially available compounds and have been converted by a three- or four-step synthesis process into the desired ligand in good yields. The compounds have been fully characterised and tested in the ROP of rac-LA under industrially relevant conditions. The complexes are based on the recently published structure [ZnCl2(TMGasme)] which has shown high activity in the polymerisation of lactide at 150 °C. Different substituents in the para-position of the guanidine moiety significantly increase the polymerisation rate whereas positioning substituents in the meta-position causes no change in the reaction rate. With molecular weights over 71 000 g mol−1 being achievable, the best system produces polymers for multiple industrial applications and its polymerisation rate approaches that of Sn(Oct)2. The robust systems are able to polymerise non-purified lactide. The initiation of the polymerisation is suggested to occur due to impurities in the monomer. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |