Academic Journal

1,2,3-Triazole-Diketopyrrolopyrrole Derivatives with Tunable Solubility and Intermolecular Interactions.

التفاصيل البيبلوغرافية
العنوان: 1,2,3-Triazole-Diketopyrrolopyrrole Derivatives with Tunable Solubility and Intermolecular Interactions.
المؤلفون: Punzi, Angela, Maiorano, Eliana, Nicoletta, Francesca, Blasi, Davide, Ardizzone, Antonio, Ventosa, Nora, Ratera, Imma, Veciana, Jaume, Farinola, Gianluca Maria
المصدر: European Journal of Organic Chemistry; May2016, p2617-2627, 11p
مصطلحات موضوعية: TRIAZOLE derivatives, PYRROLE derivatives, INTERMOLECULAR interactions, NANOSTRUCTURED materials synthesis, RING formation (Chemistry), SUBSTITUENTS (Chemistry), CLICK chemistry
مستخلص: 1,2,3-Triazole rings bearing hydrophobic aliphatic or hydrophilic oligoether chains were easily introduced at the two ends of the conjugated skeleton of bisthiophene-diketopyrrolopyrrole (TDPP) derivatives by simple click cycloaddition reactions. The combination of side chains with different structures and polarities on the triazole rings with the side chains on the N-atoms of the lactam groups of the TDPP moiety enabled the solubility and the solid-state spectroscopic properties of the resulting conjugated molecules to be tuned. Formation of nanostructured aggregates and dependence of their spectroscopic behavior on the substitution pattern were investigated. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:1434193X
DOI:10.1002/ejoc.201600120