التفاصيل البيبلوغرافية
| العنوان: |
Anion-Stoichiometry-Dependent Selectivity Enhancement in Ion-Paired Chiral Ligand–Palladium Complex Catalyzed Enantioselective Allylic Alkylation. |
| المؤلفون: |
Ohmatsu, Kohsuke, Hara, Yoshiyuki, Kusano, Yuya, Ooi, Takashi |
| المصدر: |
Synlett; 2016, Vol. 27 Issue 7, p1047-1050, 4p |
| مصطلحات موضوعية: |
STOICHIOMETRY, ENANTIOSELECTIVE catalysis, ALLYLIC alkylation, ION pairs, SUPRAMOLECULAR chemistry, CHEMICAL reactions |
| مستخلص: |
The ratio of chiral Brønsted acid to ammonium-phosphine hybrid ligand in the in situ preparation of ion-paired chiral ligands was found to have a notable effect on the stereocontrolling ability of the corresponding palladium complex. The use of supramolecular palladium complexes generated from palladium metal, ammonium phosphine, and a chiral phosphoric acid in a ratio of 1:2:3 enabled an excellent level of enantiocontrol in the catalytic asymmetric allylation of α-nitrocarboxylates with a functionalized allylic carbonate. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |