التفاصيل البيبلوغرافية
| العنوان: |
Ringing the Changes: Effects of Heterocyclic Ring Size on Stereoselectivity in [(η 5 -C 5 Me 5)RhCl], [(η 5 -C 5 Me 5)IrCl] and [Ru(η 6 -cymene)Cl] Complexes of Chiral 3-Amino-1-Azacycles. |
| المؤلفون: |
Vladimirov, Vladimir Y.1 (AUTHOR) vladimirovvy@cardiff.ac.uk, Charrier-Chardin, Matheo1 (AUTHOR), Kariuki, Benson M.1 (AUTHOR), Ward, Benjamin D.1 (AUTHOR), Newman, Paul D.1 (AUTHOR) newmanp1@cardiff.ac.uk |
| المصدر: |
Molecules. Oct2024, Vol. 29 Issue 19, p4659. 12p. |
| مصطلحات موضوعية: |
*DIAMINES, *STEREOSELECTIVE reactions, *KETONES, *TRANSFER hydrogenation |
| مستخلص: |
Ring size-dependent diastereoselective coordination of unsymmetrical diamines containing one azacyclic nitrogen and one exocyclic nitrogen to [(η5-C5Me5)MCl]+ cores where M = Rh, Ir and [Ru(η6-cymene)Cl]+ is reported herein. Total stereoselectivity was observed with the six- and seven-membered azacycles, whereas the five-derivative proved poorly selective. All complexes were active for transfer hydrogenation but showed no enantioselectivity with prochiral ketones. [ABSTRACT FROM AUTHOR] |
| قاعدة البيانات: |
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