التفاصيل البيبلوغرافية
| العنوان: |
Eco-Friendly Functionalization of Ynals with Thiols under Mild Conditions. |
| المؤلفون: |
Hanek, Kamil1 (AUTHOR) kamil.hanek@amu.edu.pl, Żak, Patrycja1 (AUTHOR) pkw@amu.edu.pl |
| المصدر: |
International Journal of Molecular Sciences. Sep2024, Vol. 25 Issue 17, p9201. 14p. |
| مصطلحات موضوعية: |
*THIOESTERS, *ORGANOCATALYSIS, *ALDEHYDES |
| مستخلص: |
A new eco-friendly method for the synthesis of mono- and multifunctional organosulfur compounds, based on the process between ynals and thiols, catalyzed by bulky N-heterocyclic carbene (NHC), was designed and optimized. The proposed organocatalytic approach allows the straightforward formation of a broad range of thioesters and sulfenyl-substituted aldehydes in yields above 86%, in mild and metal-free conditions. In this study, thirty-six sulfur-based derivatives were obtained and characterized by spectroscopic methods. [ABSTRACT FROM AUTHOR] |
| قاعدة البيانات: |
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