التفاصيل البيبلوغرافية
| العنوان: |
anti -Selective Synthesis of Substituted β-Homoprolines by Rhodium Alkyl Nitrene C–H Insertion. |
| المؤلفون: |
Tang, Xinxin1 (AUTHOR), Noda, Hidetoshi1 (AUTHOR) hnoda@bikaken.or.jp, Shibasaki, Masakatsu1 (AUTHOR) mshibasa@bikaken.or.jp |
| المصدر: |
Synlett. Jun2024, Vol. 35 Issue 10, p1131-1134. 4p. |
| مصطلحات موضوعية: |
*RHODIUM, *INDUSTRIAL chemistry, *RHODIUM catalysts, *METHOXY group, *ACID derivatives, *AZIRIDINATION |
| مستخلص: |
This article discusses the synthesis of substituted ß-homoprolines using rhodium catalysis. ß-Homoproline is a variant of ¿-proline and is found in natural products and pharmaceuticals. The article describes the development of a new method for synthesizing ß-homoprolines, which involves the cyclization of isoxazolidin-5-ones using a rhodium catalyst. The authors demonstrate the scope and limitations of this method and discuss the downstream transformations that can be performed on the resulting ß-homoprolines. Overall, this research provides valuable insights into the synthesis and potential applications of ß-homoprolines. [Extracted from the article] |
| قاعدة البيانات: |
Academic Search Index |