التفاصيل البيبلوغرافية
| العنوان: |
Structure and thermal properties of heterometallic complexes for chemical vapor deposition of Cu-Pd films. |
| المؤلفون: |
Krisyuk, V. V.1 kvv@niic.nsc.ru, Urkasym Kyzy, S.1, Baidina, I. A.1, Romanenko, G. V.2, Korolkov, I. V.1, Koretskaya, T. P.1, Petrova, N. I.1, Turgambaeva, A. E.1 |
| المصدر: |
Journal of Structural Chemistry. Dec2017, Vol. 58 Issue 8, p1522-1529. 8p. |
| مصطلحات موضوعية: |
*CHEMICAL vapor deposition, *COPPER films, *CRYSTAL structure, *PALLADIUM, *THERMAL properties |
| مستخلص: |
Novel volatile heterocomplex compounds based on copper(II) and palladium(II) fluorinated β-diketonates are studied. The crystals of the synthesized compounds are shown to be composed of 1D coordination polymers in the form of chains of alternating molecules of monometallic complexes. The crystallographic data for [Cu(hfa)2∙Pd(zif)2] are as follows: C26H22F18O10CuPd, P21/c, a = 7.9947(18) Å, b = 19.277(4) Å, c = 13.609(3) Å, β = 118.298(15)°, V = 1846.7(7) Å3, Z = 2, d = 1.810 g/cm3. The thermal properties of the compounds are examined by TG-DTA and vacuum sublimation. The complexes are studied as the precursors for producing copper-palladium alloy films by chemical vapor deposition. It is demonstrated that bimetallic alloy coatings with a ratio Cu/Pd = 1:1 can be prepared from [Cu(hfa)2∙Pd(zif)2]. [ABSTRACT FROM AUTHOR] |
| قاعدة البيانات: |
Academic Search Index |