Electronic Resource
Cumulene-like bridged indeno[1,2-b]fluorene p-conjugated polymers synthesized on metal surfaces
| العنوان: | Cumulene-like bridged indeno[1,2-b]fluorene p-conjugated polymers synthesized on metal surfaces |
|---|---|
| المؤلفون: | Martín-Fuentes, Cristina, Urgel, José I., Edalatmanesh, Shayan, Rodríguez Sánchez, Eider, Santos Barahona, José Manuel, Mutombo, Pingo, Biswas, Kalyan, Lauwaet, Koen, Gallego, José M., Miranda, Rodolfo, Jelínek, Pavel, Martín León, Nazario, Écija, David |
| بيانات النشر: | Royal Society of Chemistry 2024-01-17T13:01:11Z 2024-01-17T13:01:11Z 2021-06-30 |
| نوع الوثيقة: | Electronic Resource |
| مستخلص: | Among the plethora of polycyclic structures that have emerged in recent years, indenofluorenes comprise a unique class of compounds due to their potential in organic electronic systems such as OLEDs, OFETs, and OPVCs. However, the synthesis of fully conjugated indenofluorenes without bulky groups on the apical carbons under standard chemistry conditions is not easily accessible. In this regard, on-surface synthesis has appeared as a newly developing field of research, which exploits the use of well-defined solid surfaces as confinement templates to initiate and develop chemical reactions. Here, we demonstrate the successful fabrication of indeno[1,2-b]fluorene p-conjugated polymers linked via cumulene-like connections on well-defined metallic surfaces under ultra-high vacuum conditions. The structure and electronic properties of the formed polymers have been precisely characterized by scanning tunneling microscopy, noncontact atomic force microscopy and scanning tunneling spectroscopy, complemented by computational investigations Comunidad de Madrid Ministerio de Ciencia e Innovación MINECO Depto. de Química Orgánica Fac. de Ciencias Químicas TRUE pub |
| مصطلحات الفهرس: | 547, Química orgánica (Química), 2306 Química Orgánica, journal article, AM |
| URL: | [project QUIMTRONIC-CM (Y2018/NMT-4783)] EC FP7-PEOPLE-2011- COFUND AMAROUT II (PID2019-108532GB-I00) Grant SEV-2016-0686 |
| الاتاحة: | Open access content. Open access content embargoed access |
| ملاحظة: | application/pdf 1359-7345 English |
| Other Numbers: | ESRCM oai:docta.ucm.es:20.500.14352/93605 Chem. Commun. 2021, 57, 7545–7548 1359-7345 1364-548X 10.1039/d1cc02058g 1429623207 |
| المصدر المساهم: | REPOSITORIO E-PRINTS UNIVERSIDAD COMPLU From OAIster®, provided by the OCLC Cooperative. |
| رقم الانضمام: | edsoai.on1429623207 |
| قاعدة البيانات: | OAIster |
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