Electronic Resource
Influence of Tartrate Ligand Coordination over Luminescence Properties of Chiral Lanthanide-Based Metal–Organic Frameworks
| العنوان: | Influence of Tartrate Ligand Coordination over Luminescence Properties of Chiral Lanthanide-Based Metal–Organic Frameworks |
|---|---|
| المؤلفون: | Polímeros y Materiales Avanzados: Física, Química y Tecnología, Química aplicada, Física, Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia, Kimika aplikatua, Fisika, Huizi Rayo, Uxua, Gastearena, Xuban, Ortuño Guzmán, Ana María, Cuerva, Juan M., Rodríguez Diéguez, Antonio, García Martínez, José Angel, Ugalde Uribe-Etxebarria, Jesús, Seco Botana, José Manuel, San Sebastián Larzabal, Eider, Cepeda Ruiz, Javier |
| بيانات النشر: | MDPI 2022-11-13 |
| نوع الوثيقة: | Electronic Resource |
| مستخلص: | The present work reports on a detailed discussion about the synthesis, characterization, and luminescence properties of three pairs of enantiopure 3D metal–organic frameworks (MOFs) with general formula {[Ln2(L/D-tart)3(H2O)2]·3H2O}n (3D_Ln-L/D, where Ln = Sm(III), Eu(III) or Gd(III), and L/D-tart = L- or D-tartrate), and ten pairs of enantiopure 2D coordination polymers (CPs) with general formula [Ln(L/D-Htart)2(OH)(H2O)2]n (2D_Ln-L/D, where Ln = Y(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III) or Yb(III), and L/D-Htart = hydrogen L- or D-tartrate) based on single-crystal X-ray structures. Enantiopure nature of the samples has been further corroborated by Root Mean Square Deviation (RMSD) as well as by circular dichroism (CD) spectra. Solid-state emission spectra of Eu(III), Tb(III), and Dy(III)-based compounds confirm the occurrence of ligand-to-metal charge transfers in view of the characteristic emissions for these lanthanide ions, and emission decay curves were also recorded to estimate the emission lifetimes for the reported compounds. A complete theoretical study was accomplished to better understand the energy transfers occurring in the Eu-based counterparts, which allows for explaining the different performances of 3D-MOFs and 2D-layered compounds. As inferred from the colorimetric diagrams, emission characteristics of Eu-based 2D CPs depend on the temperature, so their luminescent thermometry has been determined on the basis of a ratiometric analysis between the ligand-centered and Eu-centered emission. Finally, a detailed study of the polarized luminescence intensity emitted by the samples is also accomplished to support the occurrence of chiro-optical activity. |
| مصطلحات الفهرس: | chiral MOFs, lanthanides, photoluminescence properties, layered compounds, luminescent thermometry, charge transfers calculation, circularly polarized light emission, info:eu-repo/semantics/article |
| URL: | 2079-4991 info:eu-repo/grantAgreement/MICIU/PGC2018-102052-A-C22 info:eu-repo/grantAgreement/MICIU/PGC2018-102052-B-C21 |
| الاتاحة: | Open access content. Open access content |
| ملاحظة: | This work has been funded by the University of the Basque Country (GIU20/028), Gobierno Vasco/Eusko Jaurlaritza (IT1755-22, IT1500-22), Junta de Andalucía (FQM-394, B-FQM-734-UGR20 and ProyExcel_00386), and the Spanish Ministry of Economy and Competitiveness (MCIU/AEI/FEDER, UE) (PGC2018-102052-A-C22, PGC2018-102052-B-C21). English |
| Other Numbers: | ESUPV oai:addi.ehu.eus:10810/58553 1364682729 |
| المصدر المساهم: | REPOSITORIO DE LA UNIVERSIDAD DEL PAIS From OAIster®, provided by the OCLC Cooperative. |
| رقم الانضمام: | edsoai.on1364682729 |
| قاعدة البيانات: | OAIster |
| ResultId |
1 |
|---|---|
| Header |
edsoai OAIster edsoai.on1364682729 877 3 Electronic Resource electronicResource 876.765686035156 |
| PLink |
https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&scope=site&db=edsoai&AN=edsoai.on1364682729&custid=s6537998&authtype=sso |
| FullText |
Array
(
[Availability] => 0
)
Array ( [0] => Array ( [Url] => http://hdl.handle.net/10810/58553# [Name] => EDS - OAIster [Category] => fullText [Text] => View record in OAIster [MouseOverText] => View record in OAIster ) ) |
| Items |
Array
(
[Name] => Title
[Label] => Title
[Group] => Ti
[Data] => Influence of Tartrate Ligand Coordination over Luminescence Properties of Chiral Lanthanide-Based Metal–Organic Frameworks
)
Array ( [Name] => Author [Label] => Authors [Group] => Au [Data] => <searchLink fieldCode="AR" term="%22Polímeros+y+Materiales+Avanzados%3A+Física%2C+Química+y+Tecnología%22">Polímeros y Materiales Avanzados: Física, Química y Tecnología</searchLink><br /><searchLink fieldCode="AR" term="%22Química+aplicada%22">Química aplicada</searchLink><br /><searchLink fieldCode="AR" term="%22Física%22">Física</searchLink><br /><searchLink fieldCode="AR" term="%22Polimero+eta+Material+Aurreratuak%3A+Fisika%2C+Kimika+eta+Teknologia%22">Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia</searchLink><br /><searchLink fieldCode="AR" term="%22Kimika+aplikatua%22">Kimika aplikatua</searchLink><br /><searchLink fieldCode="AR" term="%22Fisika%22">Fisika</searchLink><br /><searchLink fieldCode="AR" term="%22Huizi+Rayo%2C+Uxua%22">Huizi Rayo, Uxua</searchLink><br /><searchLink fieldCode="AR" term="%22Gastearena%2C+Xuban%22">Gastearena, Xuban</searchLink><br /><searchLink fieldCode="AR" term="%22Ortuño+Guzmán%2C+Ana+María%22">Ortuño Guzmán, Ana María</searchLink><br /><searchLink fieldCode="AR" term="%22Cuerva%2C+Juan+M%2E%22">Cuerva, Juan M.</searchLink><br /><searchLink fieldCode="AR" term="%22Rodríguez+Diéguez%2C+Antonio%22">Rodríguez Diéguez, Antonio</searchLink><br /><searchLink fieldCode="AR" term="%22García+Martínez%2C+José+Angel%22">García Martínez, José Angel</searchLink><br /><searchLink fieldCode="AR" term="%22Ugalde+Uribe-Etxebarria%2C+Jesús%22">Ugalde Uribe-Etxebarria, Jesús</searchLink><br /><searchLink fieldCode="AR" term="%22Seco+Botana%2C+José+Manuel%22">Seco Botana, José Manuel</searchLink><br /><searchLink fieldCode="AR" term="%22San+Sebastián+Larzabal%2C+Eider%22">San Sebastián Larzabal, Eider</searchLink><br /><searchLink fieldCode="AR" term="%22Cepeda+Ruiz%2C+Javier%22">Cepeda Ruiz, Javier</searchLink> ) Array ( [Name] => PublisherInfo [Label] => Publisher Information [Group] => [Data] => MDPI 2022-11-13 ) Array ( [Name] => TypeDocument [Label] => Document Type [Group] => TypDoc [Data] => Electronic Resource ) Array ( [Name] => Abstract [Label] => Abstract [Group] => Ab [Data] => The present work reports on a detailed discussion about the synthesis, characterization, and luminescence properties of three pairs of enantiopure 3D metal–organic frameworks (MOFs) with general formula {[Ln2(L/D-tart)3(H2O)2]·3H2O}n (3D_Ln-L/D, where Ln = Sm(III), Eu(III) or Gd(III), and L/D-tart = L- or D-tartrate), and ten pairs of enantiopure 2D coordination polymers (CPs) with general formula [Ln(L/D-Htart)2(OH)(H2O)2]n (2D_Ln-L/D, where Ln = Y(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III) or Yb(III), and L/D-Htart = hydrogen L- or D-tartrate) based on single-crystal X-ray structures. Enantiopure nature of the samples has been further corroborated by Root Mean Square Deviation (RMSD) as well as by circular dichroism (CD) spectra. Solid-state emission spectra of Eu(III), Tb(III), and Dy(III)-based compounds confirm the occurrence of ligand-to-metal charge transfers in view of the characteristic emissions for these lanthanide ions, and emission decay curves were also recorded to estimate the emission lifetimes for the reported compounds. A complete theoretical study was accomplished to better understand the energy transfers occurring in the Eu-based counterparts, which allows for explaining the different performances of 3D-MOFs and 2D-layered compounds. As inferred from the colorimetric diagrams, emission characteristics of Eu-based 2D CPs depend on the temperature, so their luminescent thermometry has been determined on the basis of a ratiometric analysis between the ligand-centered and Eu-centered emission. Finally, a detailed study of the polarized luminescence intensity emitted by the samples is also accomplished to support the occurrence of chiro-optical activity. ) Array ( [Name] => Subject [Label] => Index Terms [Group] => Su [Data] => <searchLink fieldCode="DE" term="%22chiral+MOFs%22">chiral MOFs</searchLink><br /><searchLink fieldCode="DE" term="%22lanthanides%22">lanthanides</searchLink><br /><searchLink fieldCode="DE" term="%22photoluminescence+properties%22">photoluminescence properties</searchLink><br /><searchLink fieldCode="DE" term="%22layered+compounds%22">layered compounds</searchLink><br /><searchLink fieldCode="DE" term="%22luminescent+thermometry%22">luminescent thermometry</searchLink><br /><searchLink fieldCode="DE" term="%22charge+transfers+calculation%22">charge transfers calculation</searchLink><br /><searchLink fieldCode="DE" term="%22circularly+polarized+light+emission%22">circularly polarized light emission</searchLink><br /><searchLink fieldCode="DE" term="%22info%3Aeu-repo%2Fsemantics%2Farticle%22">info:eu-repo/semantics/article</searchLink> ) Array ( [Name] => URL [Label] => URL [Group] => URL [Data] => <externalLink term="http://hdl.handle.net/10810/58553">http://hdl.handle.net/10810/58553</externalLink><br /><externalLink term="https://www.mdpi.com/2079-4991/12/22/3999">https://www.mdpi.com/2079-4991/12/22/3999</externalLink><br />2079-4991<br /><externalLink term="https://www.mdpi.com/2079-4991/12/22/3999">https://www.mdpi.com/2079-4991/12/22/3999</externalLink><br />info:eu-repo/grantAgreement/MICIU/PGC2018-102052-A-C22<br />info:eu-repo/grantAgreement/MICIU/PGC2018-102052-B-C21 ) Array ( [Name] => Avail [Label] => Availability [Group] => [Data] => Open access content. Open access content ) Array ( [Name] => Note [Label] => Note [Group] => [Data] => This work has been funded by the University of the Basque Country (GIU20/028), Gobierno Vasco/Eusko Jaurlaritza (IT1755-22, IT1500-22), Junta de Andalucía (FQM-394, B-FQM-734-UGR20 and ProyExcel_00386), and the Spanish Ministry of Economy and Competitiveness (MCIU/AEI/FEDER, UE) (PGC2018-102052-A-C22, PGC2018-102052-B-C21).<br />English ) Array ( [Name] => NumberOther [Label] => Other Numbers [Group] => [Data] => ESUPV oai:addi.ehu.eus:10810/58553<br />1364682729 ) Array ( [Name] => OtherAuthors [Label] => Contributing Source [Group] => [Data] => REPOSITORIO DE LA UNIVERSIDAD DEL PAIS<br />From OAIster®, provided by the OCLC Cooperative. ) Array ( [Name] => AN [Label] => Accession Number [Group] => ID [Data] => edsoai.on1364682729 ) |
| RecordInfo |
Array
(
[BibEntity] => Array
(
[Titles] => Array
(
[0] => Array
(
[TitleFull] => Influence of Tartrate Ligand Coordination over Luminescence Properties of Chiral Lanthanide-Based Metal–Organic Frameworks
[Type] => main
)
)
)
[BibRelationships] => Array
(
[HasContributorRelationships] => Array
(
[0] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Polímeros y Materiales Avanzados: Física, Química y Tecnología
)
)
)
[1] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Química aplicada
)
)
)
[2] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Física
)
)
)
[3] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia
)
)
)
[4] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Kimika aplikatua
)
)
)
[5] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Fisika
)
)
)
[6] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Huizi Rayo, Uxua
)
)
)
[7] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Gastearena, Xuban
)
)
)
[8] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Ortuño Guzmán, Ana María
)
)
)
[9] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Cuerva, Juan M.
)
)
)
[10] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Rodríguez Diéguez, Antonio
)
)
)
[11] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => García Martínez, José Angel
)
)
)
[12] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Ugalde Uribe-Etxebarria, Jesús
)
)
)
[13] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Seco Botana, José Manuel
)
)
)
[14] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => San Sebastián Larzabal, Eider
)
)
)
[15] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Cepeda Ruiz, Javier
)
)
)
[16] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Polímeros y Materiales Avanzados: Física, Química y Tecnología
)
)
)
[17] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Química aplicada
)
)
)
[18] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Física
)
)
)
[19] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia
)
)
)
[20] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Kimika aplikatua
)
)
)
[21] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Fisika
)
)
)
[22] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Huizi Rayo, Uxua
)
)
)
[23] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Gastearena, Xuban
)
)
)
[24] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Ortuño Guzmán, Ana María
)
)
)
[25] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Cuerva, Juan M.
)
)
)
[26] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Rodríguez Diéguez, Antonio
)
)
)
[27] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => García Martínez, José Angel
)
)
)
[28] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Ugalde Uribe-Etxebarria, Jesús
)
)
)
[29] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Seco Botana, José Manuel
)
)
)
[30] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => San Sebastián Larzabal, Eider
)
)
)
[31] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Cepeda Ruiz, Javier
)
)
)
)
[IsPartOfRelationships] => Array
(
[0] => Array
(
[BibEntity] => Array
(
[Dates] => Array
(
[0] => Array
(
[D] => 01
[M] => 01
[Type] => published
[Y] => 2022
)
)
[Identifiers] => Array
(
[0] => Array
(
[Type] => issn-locals
[Value] => edsoaiOpen
)
)
)
)
)
)
)
|
| IllustrationInfo |