التفاصيل البيبلوغرافية
| العنوان: |
Bis [4,4′-(1,3-Phenylenebis(azanylylidene))-bis(3,6-di-tert-butyl-2-oxycyclohexa-2,5-dien-1-one)-bis(dimethylsulfoxide)nickel(II)] |
| المؤلفون: |
Irina N. Meshcheryakova, Nikolay O. Druzhkov, Ilya A. Yakushev, Kseniya V. Arsenyeva, Anastasiya V. Klimashevskaya, Alexandr V. Piskunov |
| المصدر: |
Molbank, Vol 2024, Iss 4, p M1890 (2024) |
| بيانات النشر: |
MDPI AG, 2024. |
| سنة النشر: |
2024 |
| المجموعة: |
LCC:Inorganic chemistry |
| مصطلحات موضوعية: |
redox-active ligand, metal–organic cages, nickel(II), thermogravimetric analysis, X-ray diffraction analysis, UV spectroscopy, Inorganic chemistry, QD146-197 |
| الوصف: |
A new cage-like dimeric nickel(II) complex Ni2L2(DMSO)4 based on a ditopic redox-active hydroxy-para-iminobenzoquinone type ligand LH2 (L is 4,4′-(1,3-phenylene-bis(azaneylylidene))-bis(3,6-di-tert-butyl-2-oxycyclohexa-2,5-dien-1-one dianion) was synthesized in DMSO at 120 °C. The molecular structure of the synthesized compound was determined by X-ray diffraction analysis. The complex Ni2L2(DMSO)4 is almost insoluble in all organic solvents, probably due to the presence of a large number of intermolecular contacts in its structure. The electronic spectrum and thermal stability of the crystalline compound have been studied. |
| نوع الوثيقة: |
article |
| وصف الملف: |
electronic resource |
| اللغة: |
English |
| تدمد: |
1422-8599 |
| Relation: |
https://www.mdpi.com/1422-8599/2024/4/M1890; https://doaj.org/toc/1422-8599 |
| DOI: |
10.3390/M1890 |
| URL الوصول: |
https://doaj.org/article/d9ae190dd79e42da9a38b8e6d1d23ca8 |
| رقم الانضمام: |
edsdoj.9ae190dd79e42da9a38b8e6d1d23ca8 |
| قاعدة البيانات: |
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