Academic Journal
Single‐Scan Selective Excitation of Individual NMR Signals in Overlapping Multiplets
| العنوان: | Single‐Scan Selective Excitation of Individual NMR Signals in Overlapping Multiplets |
|---|---|
| المؤلفون: | Kiraly, Peter, Kern, Nicolas, Plesniak, Mateusz, Nilsson, Mathias, Procter, David, Morris, Gareth, Adams, Ralph |
| المساهمون: | University of Manchester Manchester, Laboratoire d'innovation moléculaire et applications (LIMA), Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| المصدر: | ISSN: 1433-7851. |
| بيانات النشر: | HAL CCSD Wiley-VCH Verlag |
| سنة النشر: | 2021 |
| المجموعة: | Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
| مصطلحات موضوعية: | [CHIM.ANAL]Chemical Sciences/Analytical chemistry |
| الوصف: | International audience ; 2D NMR is an immensely powerful structural tool but it is time-consuming. Targeting individual chemical groups by selective excitation in a 1D experiment can give the information required far more quickly. A major problem, however, is that proton NMR spectra are often extensively overlapped, so that in practice only a minority of sites can be selectively excited. Here we overcome that problem using a fast, single-scan method that allows selective excitation of the signals of a single proton multiplet even where it is severely overlapped by other multiplets. The advantages of the method are illustrated in a selective 1D NOESY experiment, the most efficient way to determine relative configuration unambiguously by NMR. The new approach presented here has the potential to broaden significantly the applicability of selective excitation and unlock its real potential for many other experiments. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| Relation: | hal-03425427; https://hal.archives-ouvertes.fr/hal-03425427; https://hal.archives-ouvertes.fr/hal-03425427/document; https://hal.archives-ouvertes.fr/hal-03425427/file/anie.202011642.pdf |
| DOI: | 10.1002/anie.202011642 |
| الاتاحة: | https://hal.archives-ouvertes.fr/hal-03425427 https://hal.archives-ouvertes.fr/hal-03425427/document https://hal.archives-ouvertes.fr/hal-03425427/file/anie.202011642.pdf https://doi.org/10.1002/anie.202011642 |
| Rights: | info:eu-repo/semantics/OpenAccess |
| رقم الانضمام: | edsbas.D7FC9BA |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/anie.202011642 |
|---|