Dissertation/ Thesis
偶氮苯基双亲共聚物的溶液自组装及其多重刺激响应研究 ; Study on Self-assembly Behavior and Multiple-stimuli-responsive Property of Azobenzene-based Amphiphilic Copolymers in Solution
| العنوان: | 偶氮苯基双亲共聚物的溶液自组装及其多重刺激响应研究 ; Study on Self-assembly Behavior and Multiple-stimuli-responsive Property of Azobenzene-based Amphiphilic Copolymers in Solution |
|---|---|
| المؤلفون: | 李奇 |
| المساهمون: | 许一婷 |
| المصدر: | http://210.34.4.13:8080/lunwen/detail.asp?serial=56303. |
| سنة النشر: | 2017 |
| المجموعة: | Xiamen University Institutional Repository |
| مصطلحات موضوعية: | 偶氮苯, POSS, 双亲共聚物, 聚集诱导荧光发射, 多重刺激响应, azobenzene, amphiphilic copolymer, Aggregation Induced Emission, multi-stimuli-responsive |
| الوصف: | 环境响应聚合物分子链中含有特殊的响应基团，能够对外界环境的改变做出结构和性质的调整。许多科研团队致力于设计这类聚合物，并以此来丰富其在药物传送与释放方面的应用。偶氮苯由于有独特的光响应性和还原响应性，将其嵌入到聚合物中，通过光照或加入还原性物质便可调控其自组装聚集体的结构与实现药物分子的释放等，使其成为自组装领域的研究热点。本文先合成活性的偶氮苯单体，再将其与其他响应性单体通过RAFT法进行共聚，制备出含偶氮苯基团的多重刺激响应双亲共聚物，研究了共聚物的自组装行为、胶束的荧光及控制释放性能。以下是本文的主要内容： 1.借助重氮化反应与偶合反应，制得羟基偶氮苯HOAZO。将其与酰氯反应，转变为. ; Stimuli-responsive polymeric systems integrating with special responsive moieties can undergo alteration of their chemical structures and physical properties in response to external stimulus. A great deal of work has been done to design multi-stimuli-responsive polymeric systems to enrich applications in the fields of drug controlled release. Azobenzene, as a special light and reduction dual-stimu. ; 学位：工程硕士 ; 院系专业：材料学院_工程硕士(材料工程) ; 学号：20720131150095 |
| نوع الوثيقة: | thesis |
| اللغة: | Chinese |
| Relation: | http://210.34.4.28/opac/openlink.php?strText=54574&doctype=ALL&strSearchType=callno; http://dspace.xmu.edu.cn/handle/2288/127853 |
| الاتاحة: | http://dspace.xmu.edu.cn/handle/2288/127853 |
| رقم الانضمام: | edsbas.B98F6335 |
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