Academic Journal
أعرض في EDS

Differentiating Oxygen Exchange Reaction Mechanisms across Phase Boundaries

التفاصيل البيبلوغرافية
العنوان: Differentiating Oxygen Exchange Reaction Mechanisms across Phase Boundaries
المؤلفون: Kaichuang Yang, Ying Lu, Yang Hu, Zihan Xu, Jieping Zheng, Haowen Chen, Jingle Wang, Yi Yu, Hui Zhang, Zhi Liu, Qiyang Lu
سنة النشر: 2023
مصطلحات موضوعية: Biophysics, Biochemistry, Genetics, Evolutionary Biology, Immunology, Developmental Biology, Inorganic Chemistry, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Information Systems not elsewhere classified, temperature oxygen incorporation, principle model system, different phases requires, shows excellent activity, oer mechanisms across, exploring phase engineering, >, >, oer ), electrocatalytic activity, sub ><, phase transition, phase boundary, phase boundaries, x <, sensitively probed, reaction mechanism, quite challenging, potential differences, operando <
الوصف: Triggering phase transitions by controlling the anion stoichiometry is an effective method of tuning the electrocatalytic activity of the functional oxides. However, understanding the potential differences in the reaction mechanism(s) of different phases requires the accurate mapping of phase boundaries during the electrochemical reactions, which can be quite challenging. In this work, we have established a feasible electrochemical method based on the measurement of chemical capacitance to resolve the critical stoichiometry at phase boundaries under operando conditions. We select a simple binary oxide PrO x as a proof-of-principle model system, which shows excellent activity for high-temperature oxygen incorporation and evolution reactions (OIR/OER). We show that the phase transition can be sensitively probed by quantifying the chemical capacitance, which can be further used for differentiating the OIR/OER mechanisms across the phase boundary of PrO x . Therefore, our findings provide a new framework for exploring phase engineering as a tool for the design of electrocatalysts.
نوع الوثيقة: article in journal/newspaper
اللغة: unknown
Relation: https://figshare.com/articles/journal_contribution/Differentiating_Oxygen_Exchange_Reaction_Mechanisms_across_Phase_Boundaries/24574649
DOI: 10.1021/jacs.3c09693.s001
الاتاحة: https://doi.org/10.1021/jacs.3c09693.s001
https://figshare.com/articles/journal_contribution/Differentiating_Oxygen_Exchange_Reaction_Mechanisms_across_Phase_Boundaries/24574649
Rights: CC BY-NC 4.0
رقم الانضمام: edsbas.8385E12
قاعدة البيانات: BASE
ResultId 1
Header edsbas
BASE
edsbas.8385E12
961
3
Academic Journal
academicJournal
960.976379394531
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&scope=site&db=edsbas&AN=edsbas.8385E12&custid=s6537998&authtype=sso
FullText Array ( [Availability] => 0 )
Array ( [0] => Array ( [Url] => https://doi.org/10.1021/jacs.3c09693.s001# [Name] => EDS - BASE [Category] => fullText [Text] => View record in BASE [MouseOverText] => View record in BASE ) )
Items Array ( [Name] => Title [Label] => Title [Group] => Ti [Data] => Differentiating Oxygen Exchange Reaction Mechanisms across Phase Boundaries )
Array ( [Name] => Author [Label] => Authors [Group] => Au [Data] => &lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Kaichuang+Yang%22&quot;&gt;Kaichuang Yang&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Ying+Lu%22&quot;&gt;Ying Lu&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Yang+Hu%22&quot;&gt;Yang Hu&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Zihan+Xu%22&quot;&gt;Zihan Xu&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Jieping+Zheng%22&quot;&gt;Jieping Zheng&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Haowen+Chen%22&quot;&gt;Haowen Chen&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Jingle+Wang%22&quot;&gt;Jingle Wang&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Yi+Yu%22&quot;&gt;Yi Yu&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Hui+Zhang%22&quot;&gt;Hui Zhang&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Zhi+Liu%22&quot;&gt;Zhi Liu&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Qiyang+Lu%22&quot;&gt;Qiyang Lu&lt;/searchLink&gt; )
Array ( [Name] => DatePubCY [Label] => Publication Year [Group] => Date [Data] => 2023 )
Array ( [Name] => Subject [Label] => Subject Terms [Group] => Su [Data] => &lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Biophysics%22&quot;&gt;Biophysics&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Biochemistry%22&quot;&gt;Biochemistry&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Genetics%22&quot;&gt;Genetics&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Evolutionary+Biology%22&quot;&gt;Evolutionary Biology&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Immunology%22&quot;&gt;Immunology&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Developmental+Biology%22&quot;&gt;Developmental Biology&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Inorganic+Chemistry%22&quot;&gt;Inorganic Chemistry&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Biological+Sciences+not+elsewhere+classified%22&quot;&gt;Biological Sciences not elsewhere classified&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Chemical+Sciences+not+elsewhere+classified%22&quot;&gt;Chemical Sciences not elsewhere classified&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Information+Systems+not+elsewhere+classified%22&quot;&gt;Information Systems not elsewhere classified&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22temperature+oxygen+incorporation%22&quot;&gt;temperature oxygen incorporation&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22principle+model+system%22&quot;&gt;principle model system&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22different+phases+requires%22&quot;&gt;different phases requires&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22shows+excellent+activity%22&quot;&gt;shows excellent activity&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22oer+mechanisms+across%22&quot;&gt;oer mechanisms across&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22exploring+phase+engineering%22&quot;&gt;exploring phase engineering&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22&gt;&lt;%2F+sub+&gt;%22&quot;&gt;&gt;&lt;/ sub &gt;&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22&gt;&lt;%2F+sub%22&quot;&gt;&gt;&lt;/ sub&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22oer+%29%22&quot;&gt;oer )&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22electrocatalytic+activity%22&quot;&gt;electrocatalytic activity&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22sub+&gt;&lt;%22&quot;&gt;sub &gt;&lt;&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22phase+transition%22&quot;&gt;phase transition&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22phase+boundary%22&quot;&gt;phase boundary&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22phase+boundaries%22&quot;&gt;phase boundaries&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22x+&lt;%22&quot;&gt;x &lt;&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22sensitively+probed%22&quot;&gt;sensitively probed&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22reaction+mechanism%22&quot;&gt;reaction mechanism&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22quite+challenging%22&quot;&gt;quite challenging&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22potential+differences%22&quot;&gt;potential differences&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22operando+&lt;%22&quot;&gt;operando &lt;&lt;/searchLink&gt; )
Array ( [Name] => Abstract [Label] => Description [Group] => Ab [Data] => Triggering phase transitions by controlling the anion stoichiometry is an effective method of tuning the electrocatalytic activity of the functional oxides. However, understanding the potential differences in the reaction mechanism(s) of different phases requires the accurate mapping of phase boundaries during the electrochemical reactions, which can be quite challenging. In this work, we have established a feasible electrochemical method based on the measurement of chemical capacitance to resolve the critical stoichiometry at phase boundaries under operando conditions. We select a simple binary oxide PrO x as a proof-of-principle model system, which shows excellent activity for high-temperature oxygen incorporation and evolution reactions (OIR/OER). We show that the phase transition can be sensitively probed by quantifying the chemical capacitance, which can be further used for differentiating the OIR/OER mechanisms across the phase boundary of PrO x . Therefore, our findings provide a new framework for exploring phase engineering as a tool for the design of electrocatalysts. )
Array ( [Name] => TypeDocument [Label] => Document Type [Group] => TypDoc [Data] => article in journal/newspaper )
Array ( [Name] => Language [Label] => Language [Group] => Lang [Data] => unknown )
Array ( [Name] => NoteTitleSource [Label] => Relation [Group] => SrcInfo [Data] => https://figshare.com/articles/journal_contribution/Differentiating_Oxygen_Exchange_Reaction_Mechanisms_across_Phase_Boundaries/24574649 )
Array ( [Name] => DOI [Label] => DOI [Group] => ID [Data] => 10.1021/jacs.3c09693.s001 )
Array ( [Name] => URL [Label] => Availability [Group] => URL [Data] => https://doi.org/10.1021/jacs.3c09693.s001&lt;br /&gt;https://figshare.com/articles/journal_contribution/Differentiating_Oxygen_Exchange_Reaction_Mechanisms_across_Phase_Boundaries/24574649 )
Array ( [Name] => Copyright [Label] => Rights [Group] => Cpyrght [Data] => CC BY-NC 4.0 )
Array ( [Name] => AN [Label] => Accession Number [Group] => ID [Data] => edsbas.8385E12 )
RecordInfo Array ( [BibEntity] => Array ( [Identifiers] => Array ( [0] => Array ( [Type] => doi [Value] => 10.1021/jacs.3c09693.s001 ) ) [Languages] => Array ( [0] => Array ( [Text] => unknown ) ) [Subjects] => Array ( [0] => Array ( [SubjectFull] => Biophysics [Type] => general ) [1] => Array ( [SubjectFull] => Biochemistry [Type] => general ) [2] => Array ( [SubjectFull] => Genetics [Type] => general ) [3] => Array ( [SubjectFull] => Evolutionary Biology [Type] => general ) [4] => Array ( [SubjectFull] => Immunology [Type] => general ) [5] => Array ( [SubjectFull] => Developmental Biology [Type] => general ) [6] => Array ( [SubjectFull] => Inorganic Chemistry [Type] => general ) [7] => Array ( [SubjectFull] => Biological Sciences not elsewhere classified [Type] => general ) [8] => Array ( [SubjectFull] => Chemical Sciences not elsewhere classified [Type] => general ) [9] => Array ( [SubjectFull] => Information Systems not elsewhere classified [Type] => general ) [10] => Array ( [SubjectFull] => temperature oxygen incorporation [Type] => general ) [11] => Array ( [SubjectFull] => principle model system [Type] => general ) [12] => Array ( [SubjectFull] => different phases requires [Type] => general ) [13] => Array ( [SubjectFull] => shows excellent activity [Type] => general ) [14] => Array ( [SubjectFull] => oer mechanisms across [Type] => general ) [15] => Array ( [SubjectFull] => exploring phase engineering [Type] => general ) [16] => Array ( [SubjectFull] => ></ sub > [Type] => general ) [17] => Array ( [SubjectFull] => ></ sub [Type] => general ) [18] => Array ( [SubjectFull] => oer ) [Type] => general ) [19] => Array ( [SubjectFull] => electrocatalytic activity [Type] => general ) [20] => Array ( [SubjectFull] => sub >< [Type] => general ) [21] => Array ( [SubjectFull] => phase transition [Type] => general ) [22] => Array ( [SubjectFull] => phase boundary [Type] => general ) [23] => Array ( [SubjectFull] => phase boundaries [Type] => general ) [24] => Array ( [SubjectFull] => x < [Type] => general ) [25] => Array ( [SubjectFull] => sensitively probed [Type] => general ) [26] => Array ( [SubjectFull] => reaction mechanism [Type] => general ) [27] => Array ( [SubjectFull] => quite challenging [Type] => general ) [28] => Array ( [SubjectFull] => potential differences [Type] => general ) [29] => Array ( [SubjectFull] => operando < [Type] => general ) ) [Titles] => Array ( [0] => Array ( [TitleFull] => Differentiating Oxygen Exchange Reaction Mechanisms across Phase Boundaries [Type] => main ) ) ) [BibRelationships] => Array ( [HasContributorRelationships] => Array ( [0] => Array ( [PersonEntity] => Array ( [Name] => Array ( [NameFull] => Kaichuang Yang ) ) ) [1] => Array ( [PersonEntity] => Array ( [Name] => Array ( [NameFull] => Ying Lu ) ) ) [2] => Array ( [PersonEntity] => Array ( [Name] => Array ( [NameFull] => Yang Hu ) ) ) [3] => Array ( [PersonEntity] => Array ( [Name] => Array ( [NameFull] => Zihan Xu ) ) ) [4] => Array ( [PersonEntity] => Array ( [Name] => Array ( [NameFull] => Jieping Zheng ) ) ) [5] => Array ( [PersonEntity] => Array ( [Name] => Array ( [NameFull] => Haowen Chen ) ) ) [6] => Array ( [PersonEntity] => Array ( [Name] => Array ( [NameFull] => Jingle Wang ) ) ) [7] => Array ( [PersonEntity] => Array ( [Name] => Array ( [NameFull] => Yi Yu ) ) ) [8] => Array ( [PersonEntity] => Array ( [Name] => Array ( [NameFull] => Hui Zhang ) ) ) [9] => Array ( [PersonEntity] => Array ( [Name] => Array ( [NameFull] => Zhi Liu ) ) ) [10] => Array ( [PersonEntity] => Array ( [Name] => Array ( [NameFull] => Qiyang Lu ) ) ) ) [IsPartOfRelationships] => Array ( [0] => Array ( [BibEntity] => Array ( [Dates] => Array ( [0] => Array ( [D] => 01 [M] => 01 [Type] => published [Y] => 2023 ) ) [Identifiers] => Array ( [0] => Array ( [Type] => issn-locals [Value] => edsbas ) [1] => Array ( [Type] => issn-locals [Value] => edsbas.oa ) ) ) ) ) ) )
IllustrationInfo