Academic Journal
Conversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process
| العنوان: | Conversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process |
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| المؤلفون: | Fernández-Fariña, Sandra, González-Barcia, Luis M., Romero, María J., García Tojal, Javier, Maneiro, Marcelino, Seco, José M., Zaragoza, Guillermo, Martínez-Calvo, Miguel, González-Noya, Ana M., Pedrido Castiñeiras, Rosa |
| بيانات النشر: | Royal Society of Chemistry |
| سنة النشر: | 2022 |
| المجموعة: | Repositorio Institucional de la Universidad de Burgos (RIUBU) |
| مصطلحات موضوعية: | Química inorgánica, Chemistry, Inorganic |
| الوصف: | We present the first example of a silver double-tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform giving rise to a cationic silver dihelicate [Ag2(H2L)2]SO4. This is the first silver mediated desulfurization reaction. ; FEDER cofunded-grants: from Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia, 2017 GRC GI-1682 (ED431C 2017/01), 2018 GRC GI-1584 (ED431C 2018/13), MetalBIO Network (ED431D 2017/01), Ministerio de Ciencia, Innovación y Universidades, METALBIO (CTQ2017-90802-REDT) and MultiMetDrugs (RED2018-102471-T). |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| تدمد: | 2052-1553 |
| Relation: | Inorganic Chemistry Frontiers. 2022, V. 9, n. 3, p. 531-536; https://doi.org/10.1039/D1QI01308D; info:eu-repo/grantAgreement/Xunta de Galicia//ED431C 2017%2F01; info:eu-repo/grantAgreement/Xunta de Galicia//ED431C 2018%2F13; info:eu-repo/grantAgreement/Xunta de Galicia//ED431D 2017%2F01; info:eu-repo/grantAgreement/MICIU//CTQ2017-90802-REDT; info:eu-repo/grantAgreement/MICIU//RED2018-102471-T; http://hdl.handle.net/10259/6426 |
| DOI: | 10.1039/d1qi01308d |
| الاتاحة: | http://hdl.handle.net/10259/6426 https://doi.org/10.1039/d1qi01308d |
| Rights: | info:eu-repo/semantics/embargoedAccess |
| رقم الانضمام: | edsbas.70C1A750 |
| قاعدة البيانات: | BASE |
| تدمد: | 20521553 |
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| DOI: | 10.1039/d1qi01308d |