Academic Journal
High selectivity of photocatalytic reduction of CO2 to CO based on terpyridine ligand supported CuI metal organic framework
| العنوان: | High selectivity of photocatalytic reduction of CO2 to CO based on terpyridine ligand supported CuI metal organic framework |
|---|---|
| المؤلفون: | Zhang, Wen-Dong, Wang, Yun, Liang, Yi, Jiang, Ai-Lin, Gong, Hao, Tian, Xiao-Ying, Fu, Wen-Sheng, Liao, Jia-Zhen, Chen, Peng, Ma, Ying-Zhao |
| المساهمون: | National Natural Science Foundation of China |
| المصدر: | Frontiers in Chemistry ; volume 10 ; ISSN 2296-2646 |
| بيانات النشر: | Frontiers Media SA |
| سنة النشر: | 2022 |
| المجموعة: | Frontiers (Publisher - via CrossRef) |
| الوصف: | In this work, a 4’-(4-cynaophenyl)-4,2’:6′,4-terpyridine supported Cu I MOFs photocatalyst ( Cu I MOF ) was applied to the photocatalytic CO 2 reduction for the first time. The micro-structural and physicochemical properties of the Cu I MOF were systematically studied by the powder X-ray diffraction (PXRD), Single crystal X-ray diffraction (SCXRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FT-IR), UV-Vis diffuse spectroscopy (UV-vis DRS), ns-level photoluminescence spectra (ns-level PL), Ultraviolet photoelectron spectroscopy (UPS), and N 2 adsorption-desorption test (BET-BJH). Moreover, the in situ diffuse reflectance infrared fourier transform spectroscopy ( in situ DRIFTS) was applied to investigate the adsorption and reaction intermediates of photocatalytic CO 2 reduction. As a result, Cu I MOF exhibited good performance and outstanding selectivity toward photocatalytic reduction of CO 2 to CO under full-spectrum and visible light illumination. Notably, 100% selective photocatalytic conversion of CO 2 to CO was achieved. Thus, the study presents the high selectivity and CO 2 reduction efficiency of Cu I MOF as a potential family of photocatalysts. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | unknown |
| DOI: | 10.3389/fchem.2022.974907 |
| DOI: | 10.3389/fchem.2022.974907/full |
| الاتاحة: | http://dx.doi.org/10.3389/fchem.2022.974907 https://www.frontiersin.org/articles/10.3389/fchem.2022.974907/full |
| Rights: | https://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: | edsbas.5D919C5 |
| قاعدة البيانات: | BASE |
| ResultId |
1 |
|---|---|
| Header |
edsbas BASE edsbas.5D919C5 938 3 Academic Journal academicJournal 937.599182128906 |
| PLink |
https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&scope=site&db=edsbas&AN=edsbas.5D919C5&custid=s6537998&authtype=sso |
| FullText |
Array
(
[Availability] => 0
)
Array ( [0] => Array ( [Url] => http://dx.doi.org/10.3389/fchem.2022.974907# [Name] => EDS - BASE [Category] => fullText [Text] => View record in BASE [MouseOverText] => View record in BASE ) ) |
| Items |
Array
(
[Name] => Title
[Label] => Title
[Group] => Ti
[Data] => High selectivity of photocatalytic reduction of CO2 to CO based on terpyridine ligand supported CuI metal organic framework
)
Array ( [Name] => Author [Label] => Authors [Group] => Au [Data] => <searchLink fieldCode="AR" term="%22Zhang%2C+Wen-Dong%22">Zhang, Wen-Dong</searchLink><br /><searchLink fieldCode="AR" term="%22Wang%2C+Yun%22">Wang, Yun</searchLink><br /><searchLink fieldCode="AR" term="%22Liang%2C+Yi%22">Liang, Yi</searchLink><br /><searchLink fieldCode="AR" term="%22Jiang%2C+Ai-Lin%22">Jiang, Ai-Lin</searchLink><br /><searchLink fieldCode="AR" term="%22Gong%2C+Hao%22">Gong, Hao</searchLink><br /><searchLink fieldCode="AR" term="%22Tian%2C+Xiao-Ying%22">Tian, Xiao-Ying</searchLink><br /><searchLink fieldCode="AR" term="%22Fu%2C+Wen-Sheng%22">Fu, Wen-Sheng</searchLink><br /><searchLink fieldCode="AR" term="%22Liao%2C+Jia-Zhen%22">Liao, Jia-Zhen</searchLink><br /><searchLink fieldCode="AR" term="%22Chen%2C+Peng%22">Chen, Peng</searchLink><br /><searchLink fieldCode="AR" term="%22Ma%2C+Ying-Zhao%22">Ma, Ying-Zhao</searchLink> ) Array ( [Name] => Author [Label] => Contributors [Group] => Au [Data] => National Natural Science Foundation of China ) Array ( [Name] => TitleSource [Label] => Source [Group] => Src [Data] => Frontiers in Chemistry ; volume 10 ; ISSN 2296-2646 ) Array ( [Name] => Publisher [Label] => Publisher Information [Group] => PubInfo [Data] => Frontiers Media SA ) Array ( [Name] => DatePubCY [Label] => Publication Year [Group] => Date [Data] => 2022 ) Array ( [Name] => Subset [Label] => Collection [Group] => HoldingsInfo [Data] => Frontiers (Publisher - via CrossRef) ) Array ( [Name] => Abstract [Label] => Description [Group] => Ab [Data] => In this work, a 4’-(4-cynaophenyl)-4,2’:6′,4-terpyridine supported Cu I MOFs photocatalyst ( Cu I MOF ) was applied to the photocatalytic CO 2 reduction for the first time. The micro-structural and physicochemical properties of the Cu I MOF were systematically studied by the powder X-ray diffraction (PXRD), Single crystal X-ray diffraction (SCXRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FT-IR), UV-Vis diffuse spectroscopy (UV-vis DRS), ns-level photoluminescence spectra (ns-level PL), Ultraviolet photoelectron spectroscopy (UPS), and N 2 adsorption-desorption test (BET-BJH). Moreover, the in situ diffuse reflectance infrared fourier transform spectroscopy ( in situ DRIFTS) was applied to investigate the adsorption and reaction intermediates of photocatalytic CO 2 reduction. As a result, Cu I MOF exhibited good performance and outstanding selectivity toward photocatalytic reduction of CO 2 to CO under full-spectrum and visible light illumination. Notably, 100% selective photocatalytic conversion of CO 2 to CO was achieved. Thus, the study presents the high selectivity and CO 2 reduction efficiency of Cu I MOF as a potential family of photocatalysts. ) Array ( [Name] => TypeDocument [Label] => Document Type [Group] => TypDoc [Data] => article in journal/newspaper ) Array ( [Name] => Language [Label] => Language [Group] => Lang [Data] => unknown ) Array ( [Name] => DOI [Label] => DOI [Group] => ID [Data] => 10.3389/fchem.2022.974907 ) Array ( [Name] => DOI [Label] => DOI [Group] => ID [Data] => 10.3389/fchem.2022.974907/full ) Array ( [Name] => URL [Label] => Availability [Group] => URL [Data] => http://dx.doi.org/10.3389/fchem.2022.974907<br />https://www.frontiersin.org/articles/10.3389/fchem.2022.974907/full ) Array ( [Name] => Copyright [Label] => Rights [Group] => Cpyrght [Data] => https://creativecommons.org/licenses/by/4.0/ ) Array ( [Name] => AN [Label] => Accession Number [Group] => ID [Data] => edsbas.5D919C5 ) |
| RecordInfo |
Array
(
[BibEntity] => Array
(
[Identifiers] => Array
(
[0] => Array
(
[Type] => doi
[Value] => 10.3389/fchem.2022.974907
)
)
[Languages] => Array
(
[0] => Array
(
[Text] => unknown
)
)
[Titles] => Array
(
[0] => Array
(
[TitleFull] => High selectivity of photocatalytic reduction of CO2 to CO based on terpyridine ligand supported CuI metal organic framework
[Type] => main
)
)
)
[BibRelationships] => Array
(
[HasContributorRelationships] => Array
(
[0] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Zhang, Wen-Dong
)
)
)
[1] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Wang, Yun
)
)
)
[2] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Liang, Yi
)
)
)
[3] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Jiang, Ai-Lin
)
)
)
[4] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Gong, Hao
)
)
)
[5] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Tian, Xiao-Ying
)
)
)
[6] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Fu, Wen-Sheng
)
)
)
[7] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Liao, Jia-Zhen
)
)
)
[8] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Chen, Peng
)
)
)
[9] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Ma, Ying-Zhao
)
)
)
[10] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => National Natural Science Foundation of China
)
)
)
)
[IsPartOfRelationships] => Array
(
[0] => Array
(
[BibEntity] => Array
(
[Dates] => Array
(
[0] => Array
(
[D] => 01
[M] => 01
[Type] => published
[Y] => 2022
)
)
[Identifiers] => Array
(
[0] => Array
(
[Type] => issn-locals
[Value] => edsbas
)
[1] => Array
(
[Type] => issn-locals
[Value] => edsbas.oa
)
)
[Titles] => Array
(
[0] => Array
(
[TitleFull] => Frontiers in Chemistry ; volume 10 ; ISSN 2296-2646
[Type] => main
)
)
)
)
)
)
)
|
| IllustrationInfo |