Academic Journal
Ligation of Boratabenzene and 9‑Borataphenanthrene to Coinage Metals
| العنوان: | Ligation of Boratabenzene and 9‑Borataphenanthrene to Coinage Metals |
|---|---|
| المؤلفون: | Greta K. Wisofsky (11814151), Katherine Rojales (11814154), Xiaojun Su (223221), Tyler A. Bartholome (10223646), Andrew Molino (5463602), Aishvaryadeep Kaur (4047199), David J. D. Wilson (7537427), Jason L. Dutton (1527514), Caleb D. Martin (1446844) |
| سنة النشر: | 2021 |
| المجموعة: | Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: | Biophysics, Biochemistry, Medicine, Molecular Biology, Pharmacology, Cancer, Computational Biology, Chemical Sciences not elsewhere classified, heterocyclic carbene switched, group 11 ph, carbon atom much, vacating coordination sites, 9 ‑ borataphenanthrene, 6 , 2 , 3 , copper boratabenzene species, coordination complexes, borataphenanthrene anions, metal center, coinage metals, borataalkene unit, ancillary ligand |
| الوصف: | The reactions of boratabenzene and borataphenanthrene anions with group 11 Ph 3 PMCl reagents furnished η 2 coordination complexes, with the exception of the copper boratabenzene species that adopted an η 6 mode. The binding of arene ligands to copper in an η 6 manner is rare, and altering the ancillary ligand on copper to an N-heterocyclic carbene switched the binding of the boratabenzene to η 2 , indicating that such ligands are capable of vacating coordination sites. The η 2 coordination complexes bind side-on, akin to olefins, via a borataalkene unit, although with the carbon atom much more proximal to the metal center than boron. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | unknown |
| Relation: | https://figshare.com/articles/journal_contribution/Ligation_of_Boratabenzene_and_9_Borataphenanthrene_to_Coinage_Metals/17148280 |
| DOI: | 10.1021/acs.inorgchem.1c02800.s001 |
| الاتاحة: | https://doi.org/10.1021/acs.inorgchem.1c02800.s001 |
| Rights: | CC BY-NC 4.0 |
| رقم الانضمام: | edsbas.5982BF24 |
| قاعدة البيانات: | BASE |
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