Academic Journal
Amphiphilic janus particles for aerobic alcohol oxidation in oil foams
| العنوان: | Amphiphilic janus particles for aerobic alcohol oxidation in oil foams |
|---|---|
| المؤلفون: | Wang, Kang, Davies-Jones, Josh, Graf, Arthur, Carravetta, Marina, Davies, Philip R., Pera-Titus, Marc |
| سنة النشر: | 2024 |
| المجموعة: | University of Southampton: e-Prints Soton |
| الوصف: | Amphiphilic Janus silica particles, tunable with oleophobic–oleophilic properties and low fluorine content (8 wt % F), exhibited prominent foamability for a variety of aromatic alcohols at low particle concentrations (<1 wt %) compared to randomly functionalized silica particles. When selectively loaded with Pd nanoparticles on the oleophilic hemisphere, the particles displayed more than a 2-fold increase in catalytic activity for the aerobic oxidation of benzyl alcohol compared to nonfoam bulk catalysis under ambient O2 pressure. The particles were conveniently recycled with high foamability and catalytic activity maintained for at least five consecutive runs. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | text |
| اللغة: | English |
| Relation: | https://eprints.soton.ac.uk/493200/1/Wang_al_final_pure.pdf; Wang, Kang, Davies-Jones, Josh, Graf, Arthur, Carravetta, Marina, Davies, Philip R. and Pera-Titus, Marc (2024) Amphiphilic janus particles for aerobic alcohol oxidation in oil foams. ACS Catalysis, 14 (15), 11545-11553. (doi:10.1021/acscatal.4c00909 ). |
| الاتاحة: | https://eprints.soton.ac.uk/493200/ https://eprints.soton.ac.uk/493200/1/Wang_al_final_pure.pdf |
| Rights: | cc_by_4 |
| رقم الانضمام: | edsbas.4C8FCEAD |
| قاعدة البيانات: | BASE |
| الوصف غير متاح. |