Academic Journal

Synthetic Studies of Cobalt Carbonyl by Noble Metal Catalysts. I. The Effects of the Form of Cobalt Feed and Noble Metal Catalysts

التفاصيل البيبلوغرافية
العنوان: Synthetic Studies of Cobalt Carbonyl by Noble Metal Catalysts. I. The Effects of the Form of Cobalt Feed and Noble Metal Catalysts
المؤلفون: Usami, Seiji, Kondo, Takayoshi, Nishimura, Kotaro, Koga, Yuzo
المصدر: Bulletin of the Chemical Society of Japan ; volume 42, issue 10, page 2961-2965 ; ISSN 0009-2673 1348-0634
بيانات النشر: Oxford University Press (OUP)
سنة النشر: 1969
مصطلحات موضوعية: General Chemistry
الوصف: A novel method of synthesizing cobalt carbonyl was investigated by using noble metal catalysts. It has been observed that the materials containing palladium, i. e., palladium black, palladium chloride, palladium acetylacetonate, bistriphenylphosphine dichloropalladium, and palladium-on-carriers, have a catalytic effect on the cobalt carbonylation reaction, and that palladium-on-carbon (Pd-C) is the most active catalyst. The reactivity of cobalt compounds in the cobalt carbonylation reaction catalyzed by noble metals increases in this order: CoSO4<Au>Pt>>Ag. The effect of the catalyst concentration and the activity of noble-metal catalysts were also compared with those in the case of dicobalt octacarbonyl, as an autocatalyst.
نوع الوثيقة: article in journal/newspaper
اللغة: English
DOI: 10.1246/bcsj.42.2961
الاتاحة: http://dx.doi.org/10.1246/bcsj.42.2961
https://academic.oup.com/bcsj/article-pdf/42/10/2961/55949252/bcsj.42.2961.pdf
Rights: https://academic.oup.com/pages/standard-publication-reuse-rights
رقم الانضمام: edsbas.3E5FAA39
قاعدة البيانات: BASE