Academic Journal
Corrosion Rate and Mechanism of Degradation of Chitosan/TiO 2 Coatings Deposited on MgZnCa Alloy in Hank’s Solution
العنوان: | Corrosion Rate and Mechanism of Degradation of Chitosan/TiO 2 Coatings Deposited on MgZnCa Alloy in Hank’s Solution |
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المؤلفون: | Halina Krawiec, Iryna Kozina, Maria Starowicz, Maria Lekka, Caterina Zanella, Lorenzo Fedrizzi, Michele Fedel, Flavio Deflorian |
المصدر: | International Journal of Molecular Sciences, Vol 25, Iss 10, p 5313 (2024) |
بيانات النشر: | MDPI AG |
سنة النشر: | 2024 |
المجموعة: | Directory of Open Access Journals: DOAJ Articles |
مصطلحات موضوعية: | magnesium alloy, chitosan, coating, TiO 2 nanoparticles, corrosion rate, Biology (General), QH301-705.5, Chemistry, QD1-999 |
الوصف: | Overly fast corrosion degradation of biodegradable magnesium alloys has been a major problem over the last several years. The development of protective coatings by using biocompatible, biodegradable, and non-toxic material such as chitosan ensures a reduction in the rate of corrosion of Mg alloys in simulated body fluids. In this study, chitosan/TiO 2 nanocomposite coating was used for the first time to hinder the corrosion rate of Mg19Zn1Ca alloy in Hank’s solution. The main goal of this research is to investigate and explain the corrosion degradation mechanism of Mg19Zn1Ca alloy coated by nanocomposite chitosan-based coating. The chemical composition, structural analyses, and corrosion tests were used to evaluate the protective properties of the chitosan/TiO 2 coating deposited on the Mg19Zn1Ca substrate. The chitosan/TiO 2 coating slows down the corrosion rate of the magnesium alloy by more than threefold (3.6 times). The interaction of TiO 2 (NPs) with the hydroxy and amine groups present in the chitosan molecule cause their uniform distribution in the chitosan matrix. The chitosan/TiO 2 coating limits the contact of the substrate with Hank’s solution. |
نوع الوثيقة: | article in journal/newspaper |
اللغة: | English |
تدمد: | 1422-0067 1661-6596 |
Relation: | https://www.mdpi.com/1422-0067/25/10/5313; https://doaj.org/toc/1661-6596; https://doaj.org/toc/1422-0067; https://doaj.org/article/4e6551fca5cc49b28d26b079bca53b9c |
DOI: | 10.3390/ijms25105313 |
الاتاحة: | https://doi.org/10.3390/ijms25105313 https://doaj.org/article/4e6551fca5cc49b28d26b079bca53b9c |
رقم الانضمام: | edsbas.248D9CE3 |
قاعدة البيانات: | BASE |
تدمد: | 14220067 16616596 |
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DOI: | 10.3390/ijms25105313 |