Discovery of Giant Unit-Cell Super-Structure in the Infinite-Layer Nickelate PrNiO$_2$

التفاصيل البيبلوغرافية
العنوان: Discovery of Giant Unit-Cell Super-Structure in the Infinite-Layer Nickelate PrNiO$_2$
المؤلفون: Oppliger, J., Küspert, J., Dippel, A. -C., Zimmermann, M. v., Gutowski, O., Ren, X., Zhou, X. J., Zhu, Z., Frison, R., Wang, Q., Martinelli, L., Biało, I., Chang, J.
المصدر: Commun Mater 6, 3 (2025)
سنة النشر: 2024
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Superconductivity, Condensed Matter - Materials Science
الوصف: Spectacular quantum phenomena such as superconductivity often emerge in flat-band systems where Coulomb interactions overpower electron kinetics. Engineering strategies for flat-band physics is therefore of great importance. Here, using high-energy grazing-incidence x-ray diffraction, we demonstrate how in-situ temperature annealing of the infinite-layer nickelate PrNiO$_2$ induces a giant superlattice structure. The annealing effect has a maximum well above room temperature. By covering a large scattering volume, we show a rare period-six in-plane (bi-axial) symmetry and a period-four symmetry in the out-of-plane direction. This giant unit-cell superstructure likely stems from ordering of diffusive oxygen. The stability of this superlattice structure suggests a connection to an energetically favorable electronic state of matter. As such, our study provides a new pathway - different from Moir\'e structures - to ultra-small Brillouin zone electronics.
Comment: Main: 7 pages, 4 figures. Supplementary: 2 pages, 3 figures
نوع الوثيقة: Working Paper
DOI: 10.1038/s43246-024-00729-4
URL الوصول: http://arxiv.org/abs/2404.17795
رقم الانضمام: edsarx.2404.17795
قاعدة البيانات: arXiv