X-ray photoelectron spectroscopy analyses of lithium intercalation and alloying reactions on graphite electrodes
| العنوان: | X-ray photoelectron spectroscopy analyses of lithium intercalation and alloying reactions on graphite electrodes |
|---|---|
| المؤلفون: | H. Miyadera, Seiji Takeuchi, Katsunori Nishimura, Tatsuo Horiba, Hidetoshi Honbo, Hideto Momose, Yuzo Kozono, Yasushi Muranaka |
| المصدر: | Journal of Power Sources. 68:208-211 |
| بيانات النشر: | Elsevier BV, 1997. |
| سنة النشر: | 1997 |
| مصطلحات موضوعية: | Materials science, Lithium vanadium phosphate battery, Renewable Energy, Sustainability and the Environment, Inorganic chemistry, Lithium carbonate, Intercalation (chemistry), Energy Engineering and Power Technology, chemistry.chemical_element, Lithium fluoride, Electrochemistry, chemistry.chemical_compound, chemistry, Lithium, Graphite, Electrical and Electronic Engineering, Physical and Theoretical Chemistry, Carbon |
| الوصف: | Electrochemical lithium intercalation reactions occurring in silver-supported graphite anodes were investigated by X-ray photoelectron spectroscopy (XPS). The binding energy of Li(1s) of intercalating lithium was higher than that of lithium metal, which suggests that lithium exists in the form of a positive ion in the graphite layers. The core level of the C(1s) signal of lithium intercalated graphite was higher than that of graphite, which implies that the carbon in lithium-intercalated graphite has a negative charge. This finding agrees with previous XPS studies indicating that carbon has a negative charge in a graphite-intercalation compound produced by a molten lithium intercalation reaction to graphite. Lithium carbonate, lithium fluoride and organic compounds were produced on the graphite surfaces in charge/discharge reactions in 1 M LiPF 6 /EC—DMC electrolytic solution. It was also confirmed that the initial charge current supplied to the graphite electrode with a potential between 2.8 and 0.6 V did not cause a lithium-intercalation reaction. It caused, however, other reactions such as decomposition of the electrolytic solution and production of passivating films. |
| تدمد: | 0378-7753 |
| DOI: | 10.1016/s0378-7753(96)02627-4 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::9b26ed6265f69a384282783c030fbedf https://doi.org/10.1016/s0378-7753(96)02627-4 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi...........9b26ed6265f69a384282783c030fbedf |
| قاعدة البيانات: | OpenAIRE |
| ResultId |
1 |
|---|---|
| Header |
edsair OpenAIRE edsair.doi...........9b26ed6265f69a384282783c030fbedf 775 3 unknown 774.579223632813 |
| PLink |
https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&scope=site&db=edsair&AN=edsair.doi...........9b26ed6265f69a384282783c030fbedf&custid=s6537998&authtype=sso |
| FullText |
Array
(
[Availability] => 0
)
Array ( [0] => Array ( [Url] => https://explore.openaire.eu/search/publication?articleId=doi_________::9b26ed6265f69a384282783c030fbedf# [Name] => EDS - OpenAIRE [Category] => fullText [Text] => View record in OpenAIRE [MouseOverText] => View record in OpenAIRE ) ) |
| Items |
Array
(
[Name] => Title
[Label] => Title
[Group] => Ti
[Data] => X-ray photoelectron spectroscopy analyses of lithium intercalation and alloying reactions on graphite electrodes
)
Array ( [Name] => Author [Label] => Authors [Group] => Au [Data] => <searchLink fieldCode="AR" term="%22H%2E+Miyadera%22">H. Miyadera</searchLink><br /><searchLink fieldCode="AR" term="%22Seiji+Takeuchi%22">Seiji Takeuchi</searchLink><br /><searchLink fieldCode="AR" term="%22Katsunori+Nishimura%22">Katsunori Nishimura</searchLink><br /><searchLink fieldCode="AR" term="%22Tatsuo+Horiba%22">Tatsuo Horiba</searchLink><br /><searchLink fieldCode="AR" term="%22Hidetoshi+Honbo%22">Hidetoshi Honbo</searchLink><br /><searchLink fieldCode="AR" term="%22Hideto+Momose%22">Hideto Momose</searchLink><br /><searchLink fieldCode="AR" term="%22Yuzo+Kozono%22">Yuzo Kozono</searchLink><br /><searchLink fieldCode="AR" term="%22Yasushi+Muranaka%22">Yasushi Muranaka</searchLink> ) Array ( [Name] => TitleSource [Label] => Source [Group] => Src [Data] => <i>Journal of Power Sources</i>. 68:208-211 ) Array ( [Name] => Publisher [Label] => Publisher Information [Group] => PubInfo [Data] => Elsevier BV, 1997. ) Array ( [Name] => DatePubCY [Label] => Publication Year [Group] => Date [Data] => 1997 ) Array ( [Name] => Subject [Label] => Subject Terms [Group] => Su [Data] => <searchLink fieldCode="DE" term="%22Materials+science%22">Materials science</searchLink><br /><searchLink fieldCode="DE" term="%22Lithium+vanadium+phosphate+battery%22">Lithium vanadium phosphate battery</searchLink><br /><searchLink fieldCode="DE" term="%22Renewable+Energy%2C+Sustainability+and+the+Environment%22">Renewable Energy, Sustainability and the Environment</searchLink><br /><searchLink fieldCode="DE" term="%22Inorganic+chemistry%22">Inorganic chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Lithium+carbonate%22">Lithium carbonate</searchLink><br /><searchLink fieldCode="DE" term="%22Intercalation+%28chemistry%29%22">Intercalation (chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Energy+Engineering+and+Power+Technology%22">Energy Engineering and Power Technology</searchLink><br /><searchLink fieldCode="DE" term="%22chemistry%2Echemical%5Felement%22">chemistry.chemical_element</searchLink><br /><searchLink fieldCode="DE" term="%22Lithium+fluoride%22">Lithium fluoride</searchLink><br /><searchLink fieldCode="DE" term="%22Electrochemistry%22">Electrochemistry</searchLink><br /><searchLink fieldCode="DE" term="%22chemistry%2Echemical%5Fcompound%22">chemistry.chemical_compound</searchLink><br /><searchLink fieldCode="DE" term="%22chemistry%22">chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Lithium%22">Lithium</searchLink><br /><searchLink fieldCode="DE" term="%22Graphite%22">Graphite</searchLink><br /><searchLink fieldCode="DE" term="%22Electrical+and+Electronic+Engineering%22">Electrical and Electronic Engineering</searchLink><br /><searchLink fieldCode="DE" term="%22Physical+and+Theoretical+Chemistry%22">Physical and Theoretical Chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Carbon%22">Carbon</searchLink> ) Array ( [Name] => Abstract [Label] => Description [Group] => Ab [Data] => Electrochemical lithium intercalation reactions occurring in silver-supported graphite anodes were investigated by X-ray photoelectron spectroscopy (XPS). The binding energy of Li(1s) of intercalating lithium was higher than that of lithium metal, which suggests that lithium exists in the form of a positive ion in the graphite layers. The core level of the C(1s) signal of lithium intercalated graphite was higher than that of graphite, which implies that the carbon in lithium-intercalated graphite has a negative charge. This finding agrees with previous XPS studies indicating that carbon has a negative charge in a graphite-intercalation compound produced by a molten lithium intercalation reaction to graphite. Lithium carbonate, lithium fluoride and organic compounds were produced on the graphite surfaces in charge/discharge reactions in 1 M LiPF 6 /EC—DMC electrolytic solution. It was also confirmed that the initial charge current supplied to the graphite electrode with a potential between 2.8 and 0.6 V did not cause a lithium-intercalation reaction. It caused, however, other reactions such as decomposition of the electrolytic solution and production of passivating films. ) Array ( [Name] => ISSN [Label] => ISSN [Group] => ISSN [Data] => 0378-7753 ) Array ( [Name] => DOI [Label] => DOI [Group] => ID [Data] => 10.1016/s0378-7753(96)02627-4 ) Array ( [Name] => URL [Label] => Access URL [Group] => URL [Data] => <link linkTarget="URL" linkTerm="https://explore.openaire.eu/search/publication?articleId=doi_________::9b26ed6265f69a384282783c030fbedf" linkWindow="_blank">https://explore.openaire.eu/search/publication?articleId=doi_________::9b26ed6265f69a384282783c030fbedf</link><br /><link linkTarget="URL" linkTerm="https://doi.org/10.1016/s0378-7753(96)02627-4" linkWindow="_blank">https://doi.org/10.1016/s0378-7753(96)02627-4</link> ) Array ( [Name] => Copyright [Label] => Rights [Group] => Cpyrght [Data] => CLOSED ) Array ( [Name] => AN [Label] => Accession Number [Group] => ID [Data] => edsair.doi...........9b26ed6265f69a384282783c030fbedf ) |
| RecordInfo |
Array
(
[BibEntity] => Array
(
[Identifiers] => Array
(
[0] => Array
(
[Type] => doi
[Value] => 10.1016/s0378-7753(96)02627-4
)
)
[Languages] => Array
(
[0] => Array
(
[Text] => Undetermined
)
)
[PhysicalDescription] => Array
(
[Pagination] => Array
(
[PageCount] => 4
[StartPage] => 208
)
)
[Subjects] => Array
(
[0] => Array
(
[SubjectFull] => Materials science
[Type] => general
)
[1] => Array
(
[SubjectFull] => Lithium vanadium phosphate battery
[Type] => general
)
[2] => Array
(
[SubjectFull] => Renewable Energy, Sustainability and the Environment
[Type] => general
)
[3] => Array
(
[SubjectFull] => Inorganic chemistry
[Type] => general
)
[4] => Array
(
[SubjectFull] => Lithium carbonate
[Type] => general
)
[5] => Array
(
[SubjectFull] => Intercalation (chemistry)
[Type] => general
)
[6] => Array
(
[SubjectFull] => Energy Engineering and Power Technology
[Type] => general
)
[7] => Array
(
[SubjectFull] => chemistry.chemical_element
[Type] => general
)
[8] => Array
(
[SubjectFull] => Lithium fluoride
[Type] => general
)
[9] => Array
(
[SubjectFull] => Electrochemistry
[Type] => general
)
[10] => Array
(
[SubjectFull] => chemistry.chemical_compound
[Type] => general
)
[11] => Array
(
[SubjectFull] => chemistry
[Type] => general
)
[12] => Array
(
[SubjectFull] => Lithium
[Type] => general
)
[13] => Array
(
[SubjectFull] => Graphite
[Type] => general
)
[14] => Array
(
[SubjectFull] => Electrical and Electronic Engineering
[Type] => general
)
[15] => Array
(
[SubjectFull] => Physical and Theoretical Chemistry
[Type] => general
)
[16] => Array
(
[SubjectFull] => Carbon
[Type] => general
)
)
[Titles] => Array
(
[0] => Array
(
[TitleFull] => X-ray photoelectron spectroscopy analyses of lithium intercalation and alloying reactions on graphite electrodes
[Type] => main
)
)
)
[BibRelationships] => Array
(
[HasContributorRelationships] => Array
(
[0] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => H. Miyadera
)
)
)
[1] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Seiji Takeuchi
)
)
)
[2] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Katsunori Nishimura
)
)
)
[3] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Tatsuo Horiba
)
)
)
[4] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Hidetoshi Honbo
)
)
)
[5] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Hideto Momose
)
)
)
[6] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Yuzo Kozono
)
)
)
[7] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Yasushi Muranaka
)
)
)
)
[IsPartOfRelationships] => Array
(
[0] => Array
(
[BibEntity] => Array
(
[Dates] => Array
(
[0] => Array
(
[D] => 01
[M] => 10
[Type] => published
[Y] => 1997
)
)
[Identifiers] => Array
(
[0] => Array
(
[Type] => issn-print
[Value] => 03787753
)
[1] => Array
(
[Type] => issn-locals
[Value] => edsair
)
)
[Numbering] => Array
(
[0] => Array
(
[Type] => volume
[Value] => 68
)
)
[Titles] => Array
(
[0] => Array
(
[TitleFull] => Journal of Power Sources
[Type] => main
)
)
)
)
)
)
)
|
| IllustrationInfo |