Production of Synthetic, Para-Aramid and Biopolymer Nanofibers by Immersion Rotary Jet-Spinning

التفاصيل البيبلوغرافية
العنوان: Production of Synthetic, Para-Aramid and Biopolymer Nanofibers by Immersion Rotary Jet-Spinning
المؤلفون: Isabelle Huggler, Christophe O. Chantre, Grant M. Gonzalez, Johan Ulrik Lind, Stacey A. Fitzgibbons, Kevin Kit Parker, Josue A. Goss, Luke A. MacQueen, Holly M. Golecki
المصدر: Macromolecular Materials and Engineering. 302:1600365
بيانات النشر: Wiley, 2016.
سنة النشر: 2016
مصطلحات موضوعية: chemistry.chemical_classification, Materials science, Polymers and Plastics, General Chemical Engineering, Organic Chemistry, 02 engineering and technology, Kevlar, Polymer, engineering.material, 010402 general chemistry, 021001 nanoscience & nanotechnology, Breakup, 01 natural sciences, 0104 chemical sciences, Aramid, Surface tension, chemistry, Nanofiber, Materials Chemistry, engineering, Biopolymer, Composite material, 0210 nano-technology, Spinning
الوصف: Nanofiber production platforms commonly rely on volatile carrier solvents or high voltages. Production of nanofibers comprised of charged polymers or polymers requiring nonvolatile solvents thus typically requires customization of spinning setup and polymer dope. In severe cases, these challenges can hinder fiber formation entirely. Here, a versatile system is presented which addresses these challenges by employing centrifugal force to extrude polymer dope jet through an air gap, into a flowing precipitation bath. This voltage-free approach ensures that nanofiber solidification occurs in liquid, minimizing surface tension instability that results in jet breakup and fiber defects. In addition, nanofibers of controlled size and morphology can be fabricated by tuning spinning parameters including air gap length, spinning speed, polymer concentration, and bath composition. To demonstrate the versatility of our platform, para-aramid (e.g., Kevlar) and biopolymer (e.g., DNA, alginate) nanofibers are produced that cannot be readily produced using standard nanofiber production methods.
تدمد: 1438-7492
DOI: 10.1002/mame.201600365
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::8e2c275caa505b93bca281f0dd620755
https://doi.org/10.1002/mame.201600365
Rights: CLOSED
رقم الانضمام: edsair.doi...........8e2c275caa505b93bca281f0dd620755
قاعدة البيانات: OpenAIRE