Reactions of group VIII metal carbonyl anions with 1,2-dichlorotetramethyl-disilane
| العنوان: | Reactions of group VIII metal carbonyl anions with 1,2-dichlorotetramethyl-disilane |
|---|---|
| المؤلفون: | Robert C. Kerber, Tuula Pakkanen |
| المصدر: | Inorganica Chimica Acta. 49:47-52 |
| بيانات النشر: | Elsevier BV, 1981. |
| سنة النشر: | 1981 |
| مصطلحات موضوعية: | chemistry.chemical_classification, Inorganic chemistry, chemistry.chemical_element, Salt (chemistry), Metal carbonyl, Medicinal chemistry, Inorganic Chemistry, chemistry.chemical_compound, Transition metal, chemistry, Materials Chemistry, Disilane, Physical and Theoretical Chemistry, Cobalt |
| الوصف: | Reactions of 1,2-dichlorotetramethyldisilane with transition metal carbonyl anions, NaCo(CO) 4 and Na 2 Fe(CO) 4 , proceed easily to give monodisplacement products. Thus, reaction with NaCo(CO) 4 yields a neutral chlorodisilanyl cobalt complex, Cl(CH 3 ) 2 Si(CH 3 ) 2 SiCo(CO) 4 , and the analogous reaction chlorodisilanyltetracarbonylferrate salt, [Cl(CH 3 ) 2 Si(CH 3 ) 2 SiFe(CO) 4 ] − Na + . The β-chloride of Cl(CH 3 ) 2 SiCo(CO) 4 was unreactive toward BCl 3 . Prolonged reaction with CaCo(CO) 4 resulted in formation of the cluster compound, (CO) 9 Co 3 COSi(CH 3 ) 2 Si(CH 3 ) 2 Co(CO) 4 and of bis(μ-dimethylsilylene)bis(tricarbonylcobalt)(CoCo). |
| تدمد: | 0020-1693 |
| DOI: | 10.1016/s0020-1693(00)90457-2 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::3f157d8905cbdc65ce59b9923c923737 https://doi.org/10.1016/s0020-1693(00)90457-2 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi...........3f157d8905cbdc65ce59b9923c923737 |
| قاعدة البيانات: | OpenAIRE |
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