Evaluation of catalyst leaching in silica supported zirconocene alumino hydride catalysts

التفاصيل البيبلوغرافية
العنوان: Evaluation of catalyst leaching in silica supported zirconocene alumino hydride catalysts
المؤلفون: Odilia Pérez-Camacho, Víctor Eduardo Comparán‐Padilla, Scott Collins, Catalina María Perez-Berumen, María T. Rodríguez-Hernández, Gregorio Cadenas-Pliego
المصدر: The Canadian Journal of Chemical Engineering. 95:1124-1132
بيانات النشر: Wiley, 2017.
سنة النشر: 2017
مصطلحات موضوعية: inorganic chemicals, Hydride, General Chemical Engineering, Inorganic chemistry, technology, industry, and agriculture, Methylaluminoxane, 02 engineering and technology, Polyethylene, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, 0104 chemical sciences, Catalysis, chemistry.chemical_compound, chemistry, Polymerization, High-density polyethylene, Leaching (metallurgy), 0210 nano-technology, Zirconocene dichloride
الوصف: Zirconocene aluminohydride complexes (e.g. nBuCp2ZrH3AlH2) afford higher MW polyethylene at significantly higher activity than their zirconocene dichloride counterparts (nBuCp2ZrCl2) when activated by methylaluminoxane (MAO). In this work, supported catalysts with different Al:Zr ratios on SiO2, modified with MAO were prepared, and evaluated for their tendency towards leaching in ethylene polymerization, using additional MAO or other alkylaluminum compounds. The extent of catalyst leaching was estimated by comparing kinetic data of filtered versus unfiltered catalysts during ethylene polymerization. Polydispersities and molecular weights of the HDPE obtained using filtered versus unfiltered catalysts were also compared under similar polymerization conditions. Polyethylene morphologies obtained in homogeneous and heterogeneous phase were compared by SEM. Bulk densities of the HDPE, were evaluated and related to the leaching in the polymerizations. This article is protected by copyright. All rights reserved
تدمد: 0008-4034
DOI: 10.1002/cjce.22773
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::3072cfe49ca31ad1018e2afd7d4cfe84
https://doi.org/10.1002/cjce.22773
Rights: CLOSED
رقم الانضمام: edsair.doi...........3072cfe49ca31ad1018e2afd7d4cfe84
قاعدة البيانات: OpenAIRE
الوصف
تدمد:00084034
DOI:10.1002/cjce.22773