Academic Journal
Metal-Based NLO Chromophores: from Tuning to Switching the Quadratic Nonlinearities.
العنوان: | Metal-Based NLO Chromophores: from Tuning to Switching the Quadratic Nonlinearities. |
---|---|
المؤلفون: | Le Bozec, H., Guerchais, V., Akdas-Kilig, H., Maury, O., Ordronneau, L., Boucekkine, A., Singh, A., Ledoux, I., Zyss, J. |
المصدر: | Nonlinear Optics, Quantum Optics: Concepts in Modern Optics; 2012, Vol. 43 Issue 1-4, p187-196, 10p |
مصطلحات موضوعية: | NONLINEAR optics, BIPYRIDINE, METAL complexes, LIGHT scattering, CHROMOPHORES, CHLORIDES, METAL ions, PHOTOCHROMIC materials, MAGNETIC dipoles |
مستخلص: | This article discusses the second-order nonlinear optical properties of a series of dipolar bis(dibutylaminostyryl) bipyridine M(II) dichloride complexes (M = Co, Ni, Cu, Zn) and octupolar tris(bipyridine) M(II) complexes of D |
Copyright of Nonlinear Optics, Quantum Optics: Concepts in Modern Optics is the property of Old City Publishing, Inc. and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
قاعدة البيانات: | Complementary Index |
ResultId |
1 |
---|---|
Header |
edb Complementary Index 77977886 834 6 Academic Journal academicJournal 834.063842773438 |
PLink |
https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&scope=site&db=edb&AN=77977886&custid=s6537998&authtype=sso |
FullText |
Array
(
[Availability] => 0
)
|
Items |
Array
(
[Name] => Title
[Label] => Title
[Group] => Ti
[Data] => Metal-Based NLO Chromophores: from Tuning to Switching the Quadratic Nonlinearities.
)
Array ( [Name] => Author [Label] => Authors [Group] => Au [Data] => <searchLink fieldCode="AR" term="%22Le+Bozec%2C+H%2E%22">Le Bozec, H.</searchLink><br /><searchLink fieldCode="AR" term="%22Guerchais%2C+V%2E%22">Guerchais, V.</searchLink><br /><searchLink fieldCode="AR" term="%22Akdas-Kilig%2C+H%2E%22">Akdas-Kilig, H.</searchLink><br /><searchLink fieldCode="AR" term="%22Maury%2C+O%2E%22">Maury, O.</searchLink><br /><searchLink fieldCode="AR" term="%22Ordronneau%2C+L%2E%22">Ordronneau, L.</searchLink><br /><searchLink fieldCode="AR" term="%22Boucekkine%2C+A%2E%22">Boucekkine, A.</searchLink><br /><searchLink fieldCode="AR" term="%22Singh%2C+A%2E%22">Singh, A.</searchLink><br /><searchLink fieldCode="AR" term="%22Ledoux%2C+I%2E%22">Ledoux, I.</searchLink><br /><searchLink fieldCode="AR" term="%22Zyss%2C+J%2E%22">Zyss, J.</searchLink> ) Array ( [Name] => TitleSource [Label] => Source [Group] => Src [Data] => Nonlinear Optics, Quantum Optics: Concepts in Modern Optics; 2012, Vol. 43 Issue 1-4, p187-196, 10p ) Array ( [Name] => Subject [Label] => Subject Terms [Group] => Su [Data] => <searchLink fieldCode="DE" term="%22NONLINEAR+optics%22">NONLINEAR optics</searchLink><br /><searchLink fieldCode="DE" term="%22BIPYRIDINE%22">BIPYRIDINE</searchLink><br /><searchLink fieldCode="DE" term="%22METAL+complexes%22">METAL complexes</searchLink><br /><searchLink fieldCode="DE" term="%22LIGHT+scattering%22">LIGHT scattering</searchLink><br /><searchLink fieldCode="DE" term="%22CHROMOPHORES%22">CHROMOPHORES</searchLink><br /><searchLink fieldCode="DE" term="%22CHLORIDES%22">CHLORIDES</searchLink><br /><searchLink fieldCode="DE" term="%22METAL+ions%22">METAL ions</searchLink><br /><searchLink fieldCode="DE" term="%22PHOTOCHROMIC+materials%22">PHOTOCHROMIC materials</searchLink><br /><searchLink fieldCode="DE" term="%22MAGNETIC+dipoles%22">MAGNETIC dipoles</searchLink> ) Array ( [Name] => Abstract [Label] => Abstract [Group] => Ab [Data] => This article discusses the second-order nonlinear optical properties of a series of dipolar bis(dibutylaminostyryl) bipyridine M(II) dichloride complexes (M = Co, Ni, Cu, Zn) and octupolar tris(bipyridine) M(II) complexes of D<subscript>3</subscript> symmetry (M = Fe, Ru, Os, Ni, Cu, Zn). Their quadratic NLO-susceptibilities have been determined by the Harmonic Light Scattering technique at 1.91 µm. This study shows that the optical and NLO properties are strongly influenced by the nature of the metallic centers, and the first hyperpolarizability constants β can be fine tuned by varying the nature of the metal ion. Finally, we describe an efficient strategy for the design of switchable nonlinear optical (NLO) materials. For that purpose, we have used a photochromic metal complexes which gives rise to an efficient ON/OFF reversible switching of the µ β values determined by EFISH at 1.91µ m. [ABSTRACT FROM AUTHOR] ) Array ( [Name] => Abstract [Label] => [Group] => Ab [Data] => <i>Copyright of Nonlinear Optics, Quantum Optics: Concepts in Modern Optics is the property of Old City Publishing, Inc. and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) ) |
RecordInfo |
Array
(
[BibEntity] => Array
(
[Languages] => Array
(
[0] => Array
(
[Code] => eng
[Text] => English
)
)
[PhysicalDescription] => Array
(
[Pagination] => Array
(
[PageCount] => 10
[StartPage] => 187
)
)
[Subjects] => Array
(
[0] => Array
(
[SubjectFull] => NONLINEAR optics
[Type] => general
)
[1] => Array
(
[SubjectFull] => BIPYRIDINE
[Type] => general
)
[2] => Array
(
[SubjectFull] => METAL complexes
[Type] => general
)
[3] => Array
(
[SubjectFull] => LIGHT scattering
[Type] => general
)
[4] => Array
(
[SubjectFull] => CHROMOPHORES
[Type] => general
)
[5] => Array
(
[SubjectFull] => CHLORIDES
[Type] => general
)
[6] => Array
(
[SubjectFull] => METAL ions
[Type] => general
)
[7] => Array
(
[SubjectFull] => PHOTOCHROMIC materials
[Type] => general
)
[8] => Array
(
[SubjectFull] => MAGNETIC dipoles
[Type] => general
)
)
[Titles] => Array
(
[0] => Array
(
[TitleFull] => Metal-Based NLO Chromophores: from Tuning to Switching the Quadratic Nonlinearities.
[Type] => main
)
)
)
[BibRelationships] => Array
(
[HasContributorRelationships] => Array
(
[0] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Le Bozec, H.
)
)
)
[1] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Guerchais, V.
)
)
)
[2] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Akdas-Kilig, H.
)
)
)
[3] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Maury, O.
)
)
)
[4] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Ordronneau, L.
)
)
)
[5] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Boucekkine, A.
)
)
)
[6] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Singh, A.
)
)
)
[7] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Ledoux, I.
)
)
)
[8] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Zyss, J.
)
)
)
)
[IsPartOfRelationships] => Array
(
[0] => Array
(
[BibEntity] => Array
(
[Dates] => Array
(
[0] => Array
(
[D] => 01
[M] => 10
[Text] => 2012
[Type] => published
[Y] => 2011
)
)
[Identifiers] => Array
(
[0] => Array
(
[Type] => issn-print
[Value] => 15430537
)
)
[Numbering] => Array
(
[0] => Array
(
[Type] => volume
[Value] => 43
)
[1] => Array
(
[Type] => issue
[Value] => 1-4
)
)
[Titles] => Array
(
[0] => Array
(
[TitleFull] => Nonlinear Optics, Quantum Optics: Concepts in Modern Optics
[Type] => main
)
)
)
)
)
)
)
|
IllustrationInfo |