نتائج البحث - "valorización de biomasa"

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Mechanism of glycerol dehydration and dehydrogenation: an experimental and computational correlation ; Mecanismo para la deshidratación y deshidrogenación del glicerol: correlación experimental y computacional

المؤلفون: Sanchez, Astrid, Velasquez, Mauricio, Batiot-Dupeyrat, Catherine, Espinal, Juan F., Santamaría, Alexander

المصدر: DYNA; Vol. 86 No. 208 (2019): January - March; 126-135 ; DYNA; Vol. 86 Núm. 208 (2019): Enero - Marzo; 126-135 ; 2346-2183 ; 0012-7353

مصطلحات موضوعية: hydroxyacetone formation mechanism, glycerol dehydration, glycerol dehydrogenation, glycerol conversion, biomass valorization, mecanismo de formación de hidroxiacetona, deshidratación de glicerol, deshidrogenación de glicerol, conversión de glicerol, valorización de biomasa

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Relation: https://revistas.unal.edu.co/index.php/dyna/article/view/69941/69968; https://revistas.unal.edu.co/index.php/dyna/article/view/69941/87625; https://revistas.unal.edu.co/index.php/dyna/article/view/69941

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Mechanistic and kinetic studies of benzyl alcohol photocatalytic oxidation by nanostructured titanium (hydro)oxides: do we know the entire story?

المؤلفون: Giannakoudakis, Dimitrios A., Qayyum, Abdul, Barczak, Mariusz, Colmenares Quintero, Ramón Fernando, Borowski, Piotr, Triantafyllidis, Konstantinos, Colmenares, Juan Carlos

مصطلحات موضوعية: Valorización de biomasa, Fotocatálisis, Oxidación de alcohol bencílico, Benzaldehído, Nanomateriales de TiO2, Nanotubos de titanato, Biomass valorization, Photocatalysis, Benzyl alcohol oxidation, Benzaldehyde, TiO2 nanomaterials, Titanate nanotubes

وصف الملف: 1 - 16; application/pdf

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B: Environ. 174 (2015) 96–104, https://doi.org/10.1016/j.apcatb.2015.02.028.; https://doi.org/10.1016/j.apcatb.2022.121939; https://hdl.handle.net/20.500.12494/52377; Dimitrios A. Giannakoudakis, Abdul Qayyum, Mariusz Barczak, Ramón Fernando Colmenares-Quintero, Piotr Borowski, Konstantinos Triantafyllidis, Juan Carlos Colmenares, Mechanistic and kinetic studies of benzyl alcohol photocatalytic oxidation by nanostructured titanium (hydro)oxides: Do we know the entire story?, Applied Catalysis B: Environmental, Volume 320, 2023, 121939, ISSN 0926-3373, https://doi.org/10.1016/j.apcatb.2022.121939. (https://www.sciencedirect.com/science/article/pii/S0926337322008803) Abstract: Selective upgrade of lignocellulosic biomass-derived aromatic compounds by photocatalytic oxidation is assumed as a prosperous, environmentally friendly, and cost-effective process. We present for the first time the application of various advantageous titanium oxide nano-photocatalysts for the additives-free selective partial oxidation of benzyl alcohol to benzaldehyde at ambient conditions. The two best-performing materials were found titanate nanotubes and nanocores of anatase surrounded by amorphous titanium hydroxide phase. The results obtained by scavenger tests on top of the DFT calculations led us to conclude that various reactions and active species are responsible by a complex way for materials’ photoreactivity. Depending on nanocatalysts’ physicochemical features as well as the light irradiation (ultraviolet vs. royal-blue), different mechanisms/oxidation-pathways are photo-catalyzed. Finally, we show that utilizing organic compounds like benzoquinone as scavenger hides risks due to the interactions with the targeted to be converted organic that results in elevated photolytic decomposition even under royal-blue light. Keywords: Biomass valorization; Photocatalysis; Benzyl alcohol oxidation; Benzaldehyde; TiO2 nanomaterials; Titanate nanotubes; DIMITRIOS A GIANNAKOUDAKIS, ABDUL QAYUUM, MARIUSZ BARCZAK, RAMON FERNANDO COLMENARES QUINTERO, PIOTR BOROWSKI, KONSTANTINOS TRIANTAFYLLIDIS, JUAN CARLOS COLMENARES QUINTERO, "Mechanistic and kinetic studies of benzyl alcohol photocatalytic oxidation by nanostructured titanium (hydro)oxides: do we know the entire story?" . En: Países Bajos Applied Catalysis B: Environmental ISSN: 0926-3373 ed: Elsevier Science Bv v.320 fasc.N/A p.1 - 54 ,2022, DOI:10.1016/j.apcatb.2022.121939

الاتاحة: https://hdl.handle.net/20.500.12494/52377
https://doi.org/10.1016/j.apcatb.2022.121939

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7

Dissertation/ Thesis

Estructuración de aceite de sacha inchi (plukenetia volubilis) mediante organogelificación con proteínas y methocel™ ; Structuring of sacha inchi oil (plukenetia volubilis) by means of organogelation with proteins and methocel™

المؤلفون: Lizarazo Aparicio, María Cristina

المساهمون: Gutiérrez Álvarez, Luis Felipe, Grupo de Investigación en Biomoléculas Alimentarias

مصطلحات موضوعية: 660 - Ingeniería química::664 - Tecnología de alimentos, Tecnología de alimentos, Vegetable oils, Aceites vegetales, Oleogeles, Sacha inchi, Aceites estructurados, Torta de prensa de aceite, Estabilidad oxidativa, Valorización de biomasa, Oleogels, Structured oils, Oil press-cake, Oxidative stability, Biomass valorization

وصف الملف: xi, 83 páginas; application/pdf

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Food Hydrocolloids, 138(October 2022), 108484. https://doi.org/10.1016/j.foodhyd.2023.108484; https://repositorio.unal.edu.co/handle/unal/84435; Universidad Nacional de Colombia; Repositorio Institucional Universidad Nacional de Colombia; https://repositorio.unal.edu.co/

الاتاحة: https://repositorio.unal.edu.co/handle/unal/84435
https://repositorio.unal.edu.co/

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Valorización de biomasa en productos químicos: hidrogenación de disoluciones acuosas de 5-hidroximetilfurfural en un reactor de lecho fijo utilizando catalizadores heterogéneos basados en nano partículas de metales no nobles

المؤلفون: Millet Estruch, Blanca

المصدر: RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname

مصطلحات موضوعية: 5-bis(hidroximetil)tetrahidrofurano (BHMTHF), Grado en Ingeniería Química-Grau en Enginyeria Química, Heterogeneous catalysis, Metales no nobles, Non-noble metals, Continuous flow reactor, 5-bis-(hidroximetil)furano (BHMF) y 2, Hydrogenation of 5-hydroxymethylfurfural, Reactores de lecho fijo, Biomass valorization, Catálisis heterogénea, 5-bis-(hydroxymethyl)furan (BHMF), QUIMICA ORGANICA, 5-bis(hydroxymethyl)tetrahydrofuran (BHMTHF), Hidrogenación de 5-hidroximethilfurfural, Valorización de biomasa

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URL الوصول: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::c52140bd4f204a15d121592115c62535
https://hdl.handle.net/10251/188651

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Gold nanoparticles supported on mesoporous silica as catalyst for the production of γ-valerolactone by levulinic acid hydrogenation catalysts

المؤلفون: Rodriguez Gonzalez, Carolina

المساهمون: Guerrero Fajardo, Carlos Alberto, Aprovechamiento Energético de Recursos Naturales

المصدر: Repositorio UN
Universidad Nacional de Colombia
instacron:Universidad Nacional de Colombia

مصطلحات موضوعية: mesoporous silica, sílice mesoporosa, 547 - Química orgánica [540 - Química y ciencias afines], ácido levulínico, levulinic acid, 542 - Técnicas, procedimientos, aparatos, equipos, materiales, 668 - Tecnología de otros productos orgánicos, nanopartículas de oro, Biomass valorization, 546 - Química inorgánica, 661 - Tecnología de químicos industriales, γ-valerolactone, γ-valerolactona, gold nanoparticles, Valorización de biomasa, hydrogenation, hidrogenación

وصف الملف: xix, 109 páginas; application/pdf

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https://repositorio.unal.edu.co/handle/unal/81803

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Dissertation/ Thesis

Catálisis de la hidrogenación del ácido levulínico a γ-valerolactona con nanopartículas de oro soportadas en sílice mesoporosa ; Gold nanoparticles supported on mesoporous silica as catalyst for the production of γ-valerolactone by levulinic acid hydrogenation catalysts

المؤلفون: Rodriguez Gonzalez, Carolina

المساهمون: Guerrero Fajardo, Carlos Alberto, Aprovechamiento Energético de Recursos Naturales

وصف الملف: xix, 109 páginas; application/pdf

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Zhao, “Gold nanoparticles supported on mesoporous silica: Origin of high activity and role of Au NPs in selective oxidation of cyclohexane,” Sci. Rep., vol. 6, no. 1, pp. 1–11, Jan. 2016.; R. A. Mitran, C. Matei, and D. Berger, “Correlation of mesoporous silica structural and morphological features with theoretical three-parameter model for drug release kinetics,” J. Phys. Chem. C, vol. 120, no. 51, pp. 29202–29209, 2016.; N. Syazaliyana Azali, N. Hidayatul Nazirah Kamarudin, J. Adira Jaafar, S. Najiha Timmiati, and M. Shaiful Sajab, “Modification of mesoporous silica nanoparticles with pH responsive polymer poly (2-vinylpyrrolidone) for the release of 5-Florouracil,” Mater. Today Proc., Oct. 2020.; S. A. Speakman, “Estimating Crystallite Size Using XRD Using XRD Using XRD Using XRD,” p. 105, 2011.; H. J. Yvon, “Raman Spectroscopy for Analysis and Monitoring,” Horiba Jobin Yvon, Raman Appl. Note, pp. 1–2, 2017.; A. S. Alshammari, “Heterogeneous gold catalysis: From discovery to applications,” Catalysts, vol. 9, no. 5. Multidisciplinary Digital Publishing Institute, p. 402, 29-Apr-2019.; I. Sádaba, M. López Granados, A. Riisager, and E. Taarning, “Deactivation of solid catalysts in liquid media: the case of leaching of active sites in biomass conversion reactions,” Green Chem., vol. 17, no. 8, pp. 4133–4145, Aug. 2015.; J. P. Lange, “Renewable Feedstocks: The Problem of Catalyst Deactivation and its Mitigation,” Angew. Chemie - Int. Ed., vol. 54, no. 45, pp. 13187–13197, Nov. 2015.; https://repositorio.unal.edu.co/handle/unal/81803; Universidad Nacional de Colombia; Repositorio Institucional Universidad Nacional de Colombia; https://repositorio.unal.edu.co/

الاتاحة: https://repositorio.unal.edu.co/handle/unal/81803
https://repositorio.unal.edu.co/

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11

Valorization of sawdust by conventional pyrolysis experiments

المؤلفون: Quesada Rumayor, Marina

المساهمون: Fernández Ferreras, Josefa, Universidad de Cantabria

المصدر: UCrea Repositorio Abierto de la Universidad de Cantabria
Universidad de Cantabria (UC)

مصطلحات موضوعية: Serrín, Poder calorífico, Characterization, Conventional pyrolysis, Biomass recovery, Valorización de biomasa, Wood vinegar, Sawdust, Calorific value, Caracterización, Pirólisis convencional, Vinagre de madera

URL الوصول: https://explore.openaire.eu/search/publication?articleId=RECOLECTA___::6d5d690d1e3e1f2e0e247ff9d6567866
http://hdl.handle.net/10902/22394

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12

Academic Journal

Lignina, estructura y aplicaciones: métodos de despolimerización para la obtención de derivados aromáticos de interés industrial ; Lignin, structure and applications: depolymerization methods for obtaining aromatic derivatives of industrial interest

المؤلفون: Chávez-Sifontes, Marvin, Domine, Marcelo Eduardo

المساهمون: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química, Ministerio de Ciencia e Innovación, Consejo Superior de Investigaciones Científicas

مصطلحات موضوعية: Valorización de biomasa, Despolimerización de lignina, Biopolímeros, Biorefinería, Biomass valorization, Lignin depolymerization, Biopolymers, Bio-refinery

Relation: Avances en Ciencias e Ingeniería; info:eu-repo/grantAgreement/CSIC//2009801063/; http://www.exeedu.com/publishing.cl/av_cienc_ing/; urn:issn:0718-8706; http://hdl.handle.net/10251/80767

الاتاحة: http://hdl.handle.net/10251/80767

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13

Academic Journal

Biocombustibles líquidos: procesos y tecnologías

المؤلفون: Serrano Ruiz, Juan Carlos, Luque, Rafael

مصطلحات موضوعية: Biocombustibles, Valorización de biomasa, Moléculas plataforma, Catálisis heterogénea, Química verde

Relation: RYC-2009- 04199; CTQ2011‑28954-C02-02 e IPT‑2011‑2037-310000; P10‑FQM‑6711; Serrano Ruíz, J.C., Luque R. (2011) Biocombustibles líquidos: procesos y tecnologías Anales de Química de la RSEQ 107 (4) pp. 383-389; https://hdl.handle.net/20.500.12412/5038

الاتاحة: https://hdl.handle.net/20.500.12412/5038

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14

Dissertation/ Thesis

Valorización de serrín mediante experimentos de pirólisis convencional ; Valorization of sawdust by conventional pyrolysis experiments

المؤلفون: Quesada Rumayor, Marina

المساهمون: Fernández Ferreras, Josefa, Universidad de Cantabria

مصطلحات موضوعية: Pirólisis convencional, Valorización de biomasa, Serrín, Vinagre de madera, Caracterización, Poder calorífico, Conventional pyrolysis, Biomass recovery, Sawdust, Wood vinegar, Characterization, Calorific value

Relation: http://hdl.handle.net/10902/22394

الاتاحة: http://hdl.handle.net/10902/22394

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15

Mechanism of glycerol dehydration and dehydrogenation: an experimental and computational correlation

المؤلفون: Astrid Sanchez, Catherine Batiot-Dupeyrat, Alexander Santamaría, Mauricio Velasquez, Juan F. Espinal

المصدر: DYNA, Volume: 86, Issue: 208, Pages: 126-135, Published: MAR 2019
Dyna, Vol 86, Iss 208, Pp 126-135 (2019)

مصطلحات موضوعية: lcsh:TN1-997, glycerol dehydration, 020209 energy, education, 0211 other engineering and technologies, 02 engineering and technology, lcsh:Technology, glycerol dehydrogenation, Catalysis, chemistry.chemical_compound, Computational chemistry, Phase (matter), Glyceraldehyde, glycerol conversion, 021105 building & construction, Elementary reaction, 0202 electrical engineering, electronic engineering, information engineering, Glycerol, Dehydrogenation, valorización de biomasa, conversión de glicerol, deshidrogenación de glicerol, lcsh:Mining engineering. Metallurgy, hydroxyacetone formation mechanism, Chemistry, lcsh:T, Hydroxyacetone, General Engineering, deshidratación de glicerol, biomass valorization, Pyruvaldehyde, mecanismo de formación de hidroxiacetona

وصف الملف: text/html

URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6f680610e8d6b7579020e7aac97b15f3
http://www.scielo.org.co/scielo.php?script=sci_arttext&pid=S0012-73532019000100126&lng=en&tlng=en

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16

Academic Journal

Mechanism of glycerol dehydration and dehydrogenation: an experimental and computational correlation

المؤلفون: Velásquez, Mauricio, Batiot Dupeyrat, Catherine, Espinal, Juan F., Sánchez, Astrid, Santamaría, Alexander

المصدر: DYNA: revista de la Facultad de Minas. Universidad Nacional de Colombia. Sede Medellín, ISSN 0012-7353, Vol. 86, Nº. 208, 2019, pags. 126-135

مصطلحات موضوعية: hydroxyacetone formation mechanism, glycerol dehydration, glycerol dehydrogenation, glycerol conversion, biomass valorization, mecanismo de formación de hidroxiacetona, deshidratación de glicerol, deshidrogenación de glicerol, conversión de glicerol, valorización de biomasa

وصف الملف: application/pdf

Relation: https://dialnet.unirioja.es/servlet/oaiart?codigo=6922128

الاتاحة: https://dialnet.unirioja.es/servlet/oaiart?codigo=6922128

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17

Dissertation/ Thesis

Valorización de biomasa en productos químicos: hidrogenación de disoluciones acuosas de 5-hidroximetilfurfural en un reactor de lecho fijo utilizando catalizadores heterogéneos basados en nano partículas de metales no nobles ; Chemicals from biomass: hydrogenation of aqueous solutions of 5-hydroxymethylfurfural in a fixed bed reactor using non-noble metals nanoparticles as heterogeneous catalysts ; Valorització de biomassa en productes químics: hidrogenació de dissolucions aquoses de 5-hidroximetilfurfural en un reactor de llit fix utilitzant catalitzadors heterogenis basats en nanopartícules de metalls no nobles

المؤلفون: Millet Estruch, Blanca

المساهمون: Iborra Chornet, Sara, Climent Olmedo, María José, Arias Carrascal, Karen Sulay, Universitat Politècnica de València. Departamento de Química - Departament de Química, Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials

مصطلحات موضوعية: Valorización de biomasa, Catálisis heterogénea, Hidrogenación de 5-hidroximethilfurfural, Metales no nobles, 5-bis-(hidroximetil)furano (BHMF) y 2, 5-bis(hidroximetil)tetrahidrofurano (BHMTHF), Reactores de lecho fijo, Biomass valorization, Heterogeneous catalysis, Hydrogenation of 5-hydroxymethylfurfural, Non-noble metals, 5-bis-(hydroxymethyl)furan (BHMF), 5-bis(hydroxymethyl)tetrahydrofuran (BHMTHF), Continuous flow reactor, QUIMICA ORGANICA, Grado en Ingeniería Química-Grau en Enginyeria Química