المؤلفون: Yannick Stöckl, Katrin Gugeler, Celine M. Holzwarth, Wolfgang Frey, Sascha Wegner, Birgit Claasen, Anna Zens, Dietrich Gudat, Christian P. Sindlinger, Johannes Kästner, Sabine Laschat

مصطلحات موضوعية: Biochemistry, Microbiology, Genetics, Evolutionary Biology, Chemical Sciences not elsewhere classified, Information Systems not elsewhere classified, unexpected steric effects, reaction intermediate could, likely reaction path, characterized using heteronuclear, challenging synthesis makes, additional experiments indicated, borate formation governs, successful chirality transfer, >- chelate effect, n , chirality transfer, borate anion, type breaking, stereocontrol prompted, quite robust, organometallic nucleophile, nmr spectroscopy, n <, methodology proved, luminescent properties, inverse enantioselectivity, holistic understanding, earlier work, dft calculations

Relation: https://figshare.com/articles/journal_contribution/Chirality_Transfer_of_Stereogenic_Boron_Centers_Enabled_by_a_S_sub_N_sub_2_Type_Mechanism/25003380

الاتاحة: https://doi.org/10.1021/acs.organomet.3c00472.s001
https://figshare.com/articles/journal_contribution/Chirality_Transfer_of_Stereogenic_Boron_Centers_Enabled_by_a_S_sub_N_sub_2_Type_Mechanism/25003380

المؤلفون: Yannick Stöckl, Katrin Gugeler, Celine M. Holzwarth, Wolfgang Frey, Sascha Wegner, Birgit Claasen, Anna Zens, Dietrich Gudat, Christian P. Sindlinger, Johannes Kästner, Sabine Laschat

مصطلحات موضوعية: Biochemistry, Microbiology, Genetics, Evolutionary Biology, Chemical Sciences not elsewhere classified, Information Systems not elsewhere classified, unexpected steric effects, reaction intermediate could, likely reaction path, characterized using heteronuclear, challenging synthesis makes, additional experiments indicated, borate formation governs, successful chirality transfer, >- chelate effect, n , chirality transfer, borate anion, type breaking, stereocontrol prompted, quite robust, organometallic nucleophile, nmr spectroscopy, n <, methodology proved, luminescent properties, inverse enantioselectivity, holistic understanding, earlier work, dft calculations

Relation: https://figshare.com/articles/dataset/Chirality_Transfer_of_Stereogenic_Boron_Centers_Enabled_by_a_S_sub_N_sub_2_Type_Mechanism/25003383

الاتاحة: https://doi.org/10.1021/acs.organomet.3c00472.s002
https://figshare.com/articles/dataset/Chirality_Transfer_of_Stereogenic_Boron_Centers_Enabled_by_a_S_sub_N_sub_2_Type_Mechanism/25003383