المؤلفون: Yigao Li, Zhuang Meng, Xinju Zhu, Xin-Qi Hao, Mao-Ping Song

مصطلحات موضوعية: Biochemistry, Medicine, Neuroscience, Ecology, Mental Health, Computational Biology, Chemical Sciences not elsewhere classified, sulfonyl radical might, novel sulfonylating reagent, mechanistic studies revealed, current protocol featured, cheap metal catalysis, also successfully realized, arenes using tosmic, well tolerated, para <, ortho <, operational convenience, naphthalene substrate, including indolines, good yields, corresponding products, broad range, assisted direct

Relation: https://figshare.com/articles/journal_contribution/Cu_II_-Mediated_Sulfonylation_of_Hetero_arenes_with_TosMIC_Using_Monodentate_Directing_Groups/25266771

الاتاحة: https://doi.org/10.1021/acs.joc.3c02730.s001
https://figshare.com/articles/journal_contribution/Cu_II_-Mediated_Sulfonylation_of_Hetero_arenes_with_TosMIC_Using_Monodentate_Directing_Groups/25266771

المؤلفون: Andrei Chirila, Yiqin Hu, John C. Linehan, David A. Dixon, Eric S. Wiedner

مصطلحات موضوعية: Biophysics, Biochemistry, Biotechnology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, sup >–, sup >+, studies significantly expand, electronic structure theory, minimal energy losses, mechanistic studies revealed, kinetic activity descriptors, dmpe )< sub, 2 , rhodium catalyst proved, efficiently utilize h, ketones activity descriptors, cobalt catalyst could, thermodynamic hydricity values, thermodynamic hydricity descriptor, develop kinetic descriptors, kinetic descriptors, energy relationships, analysis revealed, known hydricity, efficient catalyst, wide range, valid approach, two complexes, tetrahydrofuran solvents

Relation: https://figshare.com/articles/journal_contribution/Thermodynamic_and_Kinetic_Activity_Descriptors_for_the_Catalytic_Hydrogenation_of_Ketones/25336089

الاتاحة: https://doi.org/10.1021/jacs.3c13876.s001
https://figshare.com/articles/journal_contribution/Thermodynamic_and_Kinetic_Activity_Descriptors_for_the_Catalytic_Hydrogenation_of_Ketones/25336089

المؤلفون: Andrei Chirila, Yiqin Hu, John C. Linehan, David A. Dixon, Eric S. Wiedner

مصطلحات موضوعية: Biophysics, Biochemistry, Biotechnology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, sup >–, sup >+, studies significantly expand, electronic structure theory, minimal energy losses, mechanistic studies revealed, kinetic activity descriptors, dmpe )< sub, 2 , rhodium catalyst proved, efficiently utilize h, ketones activity descriptors, cobalt catalyst could, thermodynamic hydricity values, thermodynamic hydricity descriptor, develop kinetic descriptors, kinetic descriptors, energy relationships, analysis revealed, known hydricity, efficient catalyst, wide range, valid approach, two complexes, tetrahydrofuran solvents

Relation: https://figshare.com/articles/journal_contribution/Thermodynamic_and_Kinetic_Activity_Descriptors_for_the_Catalytic_Hydrogenation_of_Ketones/25336092

الاتاحة: https://doi.org/10.1021/jacs.3c13876.s002
https://figshare.com/articles/journal_contribution/Thermodynamic_and_Kinetic_Activity_Descriptors_for_the_Catalytic_Hydrogenation_of_Ketones/25336092

المؤلفون: Jingya Yang, Cunhui Wang, Bao Huang, Hongyan Zhou, Jiangjiang Li, Xiaojun Liu

مصطلحات موضوعية: Biophysics, Biochemistry, Medicine, Microbiology, Molecular Biology, Immunology, Cancer, Virology, Computational Biology, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, visible light irradiation, remains highly challenging, reactions proceeded smoothly, photoredox catalytic phosphine, mediated deoxygenative hydroacylation, mediated c –, mechanistic studies revealed, 6 , 3 , n <, precise preparation, delivering various, carboxylic acids, bond cleavage, >′- diarylhydrazides

Relation: https://figshare.com/articles/journal_contribution/Photoredox_Catalytic_Phosphine-Mediated_Deoxygenative_Hydroacylation_of_Azobenzenes_with_Carboxylic_Acids/24969510

الاتاحة: https://doi.org/10.1021/acs.orglett.3c03875.s001
https://figshare.com/articles/journal_contribution/Photoredox_Catalytic_Phosphine-Mediated_Deoxygenative_Hydroacylation_of_Azobenzenes_with_Carboxylic_Acids/24969510

المؤلفون: Chong-Yu Liu, Jin Zhao, Cheng-Xue Pan, Dong-Liang Mo, Xiao-Pan Ma, Wan-Yun Huang

مصطلحات موضوعية: Biophysics, Biochemistry, Physiology, Computational Biology, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, quinoline scaffold diversity, prepare various tetrahydrobenzofuro, mechanistic studies revealed, intramolecular cyclization process, cyclization cascade herein, )- catalyzed dearomatization, 2 ‑( chloromethyl, 2 -( quinolin, 2 -( chloromethyl, radical addition dearomatization, radical addition, 2 -<, radical precursors, excellent yields, b <, >] quinolines

Relation: https://figshare.com/articles/journal_contribution/Copper_I_-Catalyzed_Dearomatization_of_Benzofurans_with_2_Chloromethyl_anilines_through_Radical_Addition_and_Cyclization_Cascade/24964196

الاتاحة: https://doi.org/10.1021/acs.orglett.3c03964.s001
https://figshare.com/articles/journal_contribution/Copper_I_-Catalyzed_Dearomatization_of_Benzofurans_with_2_Chloromethyl_anilines_through_Radical_Addition_and_Cyclization_Cascade/24964196

المؤلفون: Yan Du, Jing-Jing Tang, Yarong Wang, Junhao Hu, Changhua Chen, Zhonggui Xiong, Yang Li, Jiangli Fan, Ming Bao, Xiaoqiang Yu

مصطلحات موضوعية: Neuroscience, Biotechnology, Hematology, Infectious Diseases, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, sextet ground state, quartet spin state, mechanistic studies revealed, h atom abstraction, computational studies showed, reaction proceeded via, bounding iron species, reaction proceeds, driven iron, mild conditions, good yields, free conditions, features satisfactory, diphenylmethane derivatives, determining step, catalyzed c

Relation: https://figshare.com/articles/journal_contribution/Visible-Light-Driven_Iron-Catalyzed_Intermolecular_Benzylic_C_sp_sup_3_sup_H_Amination_with_1_2_3_4-Tetrazoles/25006488

الاتاحة: https://doi.org/10.1021/acs.orglett.3c04048.s001
https://figshare.com/articles/journal_contribution/Visible-Light-Driven_Iron-Catalyzed_Intermolecular_Benzylic_C_sp_sup_3_sup_H_Amination_with_1_2_3_4-Tetrazoles/25006488

المؤلفون: Yuki Saito, Yuki Sato, Shu̅ Kobayashi

مصطلحات موضوعية: Biochemistry, Developmental Biology, Cancer, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, reported flow hydrogenations, mechanistic studies revealed, flow enantioselective cyclization, flow conditions revealed, amines could improve, 2 , sophisticated catalysis, rh catalyst, hydrogen gas, high yields, heteropoly acids, heteropoly acid, heterogeneous catalysts, functionalized sio, efficient mass, composites developed, catalyst performance, catalyst deactivation

Relation: https://figshare.com/articles/journal_contribution/Continuous-Flow_Enantioselective_Hydrogenative_Enyne_Cyclization_with_Chiral_Heterogeneous_Rh_Catalysts/25078134

الاتاحة: https://doi.org/10.1021/acscatal.3c05868.s001
https://figshare.com/articles/journal_contribution/Continuous-Flow_Enantioselective_Hydrogenative_Enyne_Cyclization_with_Chiral_Heterogeneous_Rh_Catalysts/25078134

المؤلفون: Yang Gao, Baiyang Jiang, Nathan C. Friede, Arianne C. Hunter, Dylan G. Boucher, Shelley D. Minteer, Matthew S. Sigman, Sarah E. Reisman, Phil S. Baran

مصطلحات موضوعية: Biochemistry, Medicine, Microbiology, Genetics, Molecular Biology, Biotechnology, Plant Biology, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, using catalytic tetrakis, mild reductive electrolysis, mechanistic studies revealed, key reductive mediator, electrocatalytic decarboxylative approach, chiral secondary alcohols, asymmetric alkyl e, alkyl nucleophile synthons, via redox, successfully applied, organic reductants, natural products, high enantioselectivity, good yield, functional groups, enabling additives, dramatically simplify, disclosed herein, coupling reactions, broad range

Relation: https://figshare.com/articles/journal_contribution/Electrocatalytic_Asymmetric_Nozaki_Hiyama_Kishi_Decarboxylative_Coupling_Scope_Applications_and_Mechanism/25176544

الاتاحة: https://doi.org/10.1021/jacs.3c13442.s001
https://figshare.com/articles/journal_contribution/Electrocatalytic_Asymmetric_Nozaki_Hiyama_Kishi_Decarboxylative_Coupling_Scope_Applications_and_Mechanism/25176544

المؤلفون: Meilan Pan, Cong Li, Xiuzhen Wei, Guanyu Liu, Edison Huixiang Ang, Bingjun Pan

مصطلحات موضوعية: Biophysics, Biotechnology, Cancer, Inorganic Chemistry, Space Science, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, sup >+, resulted hybrid nanocomposite, mechanistic studies revealed, interfacial electric field, halogenated organic pollutants, external energy input, enhanced electron transfer, effectively break c, comsol simulations confirmed, 3 , 2 , efficiently capture h, driven atomic hydrogen, piezoelectric process independent, dotted ni nanoparticles, atomic hydrogen, subtly dotted, pioneering piezoelectric, process mediated, work introduces, ultrasonic vibration, surface charge, significant challenge

Relation: https://figshare.com/articles/journal_contribution/Pioneering_Piezoelectric-Driven_Atomic_Hydrogen_for_Efficient_Dehalogenation_of_Halogenated_Organic_Pollutants/25210961

الاتاحة: https://doi.org/10.1021/acs.est.3c09579.s001
https://figshare.com/articles/journal_contribution/Pioneering_Piezoelectric-Driven_Atomic_Hydrogen_for_Efficient_Dehalogenation_of_Halogenated_Organic_Pollutants/25210961

المؤلفون: Matthew J. Bock, Scott. E. Denmark

مصطلحات موضوعية: Biochemistry, Medicine, Microbiology, Cell Biology, Molecular Biology, Immunology, Space Science, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, two literature examples, parallel experimentation revealed, mechanistic studies revealed, enables successful cross, boronic ester skeleton, method described herein, neopentyldiol alkylboronic esters, boronic esters, alkylboronic esters, stereoretentive pathway, reactions proceed, reaction proceeds, reach completion, previously took, predominant pathway, potassium trimethylsilanolate, l <, high linear, good yields, deleterious protodehalogenation

Relation: https://figshare.com/articles/journal_contribution/Rapid_Homogenous_B_Alkyl_Suzuki_Miyaura_Cross-Coupling_of_Boronic_Esters/25407507

الاتاحة: https://doi.org/10.1021/acs.joc.4c00089.s001

المؤلفون: Yuki Saito, Yuki Sato, Shu̅ Kobayashi

مصطلحات موضوعية: Biochemistry, Developmental Biology, Cancer, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, reported flow hydrogenations, mechanistic studies revealed, flow enantioselective cyclization, flow conditions revealed, amines could improve, 2 , sophisticated catalysis, rh catalyst, hydrogen gas, high yields, heteropoly acids, heteropoly acid, heterogeneous catalysts, functionalized sio, efficient mass, composites developed, catalyst performance, catalyst deactivation

Relation: https://figshare.com/articles/journal_contribution/Continuous-Flow_Enantioselective_Hydrogenative_Enyne_Cyclization_with_Chiral_Heterogeneous_Rh_Catalysts/25078134

الاتاحة: https://doi.org/10.1021/acscatal.3c05868.s001

المؤلفون: Yang Gao, Baiyang Jiang, Nathan C. Friede, Arianne C. Hunter, Dylan G. Boucher, Shelley D. Minteer, Matthew S. Sigman, Sarah E. Reisman, Phil S. Baran

مصطلحات موضوعية: Biochemistry, Medicine, Microbiology, Genetics, Molecular Biology, Biotechnology, Plant Biology, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, using catalytic tetrakis, mild reductive electrolysis, mechanistic studies revealed, key reductive mediator, electrocatalytic decarboxylative approach, chiral secondary alcohols, asymmetric alkyl e, alkyl nucleophile synthons, via redox, successfully applied, organic reductants, natural products, high enantioselectivity, good yield, functional groups, enabling additives, dramatically simplify, disclosed herein, coupling reactions, broad range

Relation: https://figshare.com/articles/journal_contribution/Electrocatalytic_Asymmetric_Nozaki_Hiyama_Kishi_Decarboxylative_Coupling_Scope_Applications_and_Mechanism/25176544

الاتاحة: https://doi.org/10.1021/jacs.3c13442.s001

المؤلفون: Meilan Pan, Cong Li, Xiuzhen Wei, Guanyu Liu, Edison Huixiang Ang, Bingjun Pan

مصطلحات موضوعية: Biophysics, Biotechnology, Cancer, Inorganic Chemistry, Space Science, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, sup >+, resulted hybrid nanocomposite, mechanistic studies revealed, interfacial electric field, halogenated organic pollutants, external energy input, enhanced electron transfer, effectively break c, comsol simulations confirmed, 3 , 2 , efficiently capture h, driven atomic hydrogen, piezoelectric process independent, dotted ni nanoparticles, atomic hydrogen, subtly dotted, pioneering piezoelectric, process mediated, work introduces, ultrasonic vibration, surface charge, significant challenge

Relation: https://figshare.com/articles/journal_contribution/Pioneering_Piezoelectric-Driven_Atomic_Hydrogen_for_Efficient_Dehalogenation_of_Halogenated_Organic_Pollutants/25210961

الاتاحة: https://doi.org/10.1021/acs.est.3c09579.s001

المؤلفون: Yigao Li, Zhuang Meng, Xinju Zhu, Xin-Qi Hao, Mao-Ping Song

مصطلحات موضوعية: Biochemistry, Medicine, Neuroscience, Ecology, Mental Health, Computational Biology, Chemical Sciences not elsewhere classified, sulfonyl radical might, novel sulfonylating reagent, mechanistic studies revealed, current protocol featured, cheap metal catalysis, also successfully realized, arenes using tosmic, well tolerated, para <, ortho <, operational convenience, naphthalene substrate, including indolines, good yields, corresponding products, broad range, assisted direct

Relation: https://figshare.com/articles/journal_contribution/Cu_II_-Mediated_Sulfonylation_of_Hetero_arenes_with_TosMIC_Using_Monodentate_Directing_Groups/25266771

الاتاحة: https://doi.org/10.1021/acs.joc.3c02730.s001

المؤلفون: Andrei Chirila, Yiqin Hu, John C. Linehan, David A. Dixon, Eric S. Wiedner

مصطلحات موضوعية: Biophysics, Biochemistry, Biotechnology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, sup >–, sup >+, studies significantly expand, electronic structure theory, minimal energy losses, mechanistic studies revealed, kinetic activity descriptors, dmpe )< sub, 2 , rhodium catalyst proved, efficiently utilize h, ketones activity descriptors, cobalt catalyst could, thermodynamic hydricity values, thermodynamic hydricity descriptor, develop kinetic descriptors, kinetic descriptors, energy relationships, analysis revealed, known hydricity, efficient catalyst, wide range, valid approach, two complexes, tetrahydrofuran solvents

Relation: https://figshare.com/articles/journal_contribution/Thermodynamic_and_Kinetic_Activity_Descriptors_for_the_Catalytic_Hydrogenation_of_Ketones/25336089

الاتاحة: https://doi.org/10.1021/jacs.3c13876.s001

المؤلفون: Andrei Chirila, Yiqin Hu, John C. Linehan, David A. Dixon, Eric S. Wiedner

مصطلحات موضوعية: Biophysics, Biochemistry, Biotechnology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, sup >–, sup >+, studies significantly expand, electronic structure theory, minimal energy losses, mechanistic studies revealed, kinetic activity descriptors, dmpe )< sub, 2 , rhodium catalyst proved, efficiently utilize h, ketones activity descriptors, cobalt catalyst could, thermodynamic hydricity values, thermodynamic hydricity descriptor, develop kinetic descriptors, kinetic descriptors, energy relationships, analysis revealed, known hydricity, efficient catalyst, wide range, valid approach, two complexes, tetrahydrofuran solvents

Relation: https://figshare.com/articles/journal_contribution/Thermodynamic_and_Kinetic_Activity_Descriptors_for_the_Catalytic_Hydrogenation_of_Ketones/25336092

الاتاحة: https://doi.org/10.1021/jacs.3c13876.s002

المؤلفون: Puranjan Chatterjee, Yong Han, Takeshi Kobayashi, Krishna Kamlesh Verma, Marco Mais, Ranjan K. Behera, Thomas H. Johnson, Tanya Prozorov, James W. Evans, Igor I. Slowing, Wenyu Huang

مصطلحات موضوعية: Biophysics, Medicine, Genetics, Physiology, Biotechnology, Ecology, Inorganic Chemistry, Hematology, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, framework al suggested, synthetic aluminosilicate mcm, brønsted acid sites, mechanistic studies revealed, surface sites, aluminosilicate materials, mechanistic understanding, mechanistic study, theoretical calculations, surface charge, spectroscopic analysis, solution indicated, new platform, mechanism underlying, heavy rare, electrostatic interaction, earth elements, earth element, capturing rare

Relation: https://figshare.com/articles/journal_contribution/Capturing_Rare-Earth_Elements_by_Synthetic_Aluminosilicate_MCM-22_Mechanistic_Understanding_of_Yb_III_Capture/24518757

الاتاحة: https://doi.org/10.1021/acsami.3c14560.s001
https://figshare.com/articles/journal_contribution/Capturing_Rare-Earth_Elements_by_Synthetic_Aluminosilicate_MCM-22_Mechanistic_Understanding_of_Yb_III_Capture/24518757

المؤلفون: Jaya Bharti, Lingjing Chen, Zhenguo Guo, Lin Cheng, Joël Wellauer, Oliver S. Wenger, Niklas von Wolff, Kai-Chung Lau, Tai-Chu Lau, Gui Chen, Marc Robert

مصطلحات موضوعية: Biophysics, Biochemistry, Cell Biology, Physiology, Immunology, Marine Biology, Infectious Diseases, Biological Sciences not elsewhere classified, Information Systems not elsewhere classified, two cu centers, sacrificial electron donors, acetonitrile solutions using, 2 +, intermediate hydride species, mechanistic studies revealed, generate formate following, different pathways visible, 2 , mechanistic studies, bridging hydride, weak acid, turnover number, second product, reduced complex, reaction rate, proton source, previously shown, observed reactivity, homobimetallic complexes, also produced

Relation: https://figshare.com/articles/journal_contribution/Visible-Light-Driven_CO_sub_2_sub_Reduction_with_Homobimetallic_Complexes_Cooperativity_between_Metals_and_Activation_of_Different_Pathways/24541663

الاتاحة: https://doi.org/10.1021/jacs.3c07799.s001
https://figshare.com/articles/journal_contribution/Visible-Light-Driven_CO_sub_2_sub_Reduction_with_Homobimetallic_Complexes_Cooperativity_between_Metals_and_Activation_of_Different_Pathways/24541663

المؤلفون: Hao Yuan, Yu-Zheng Wu, Yu-Han Fang, Chun-Hua Chen, Cui Liang, Dong-Liang Mo

مصطلحات موضوعية: Biochemistry, Medicine, Genetics, Molecular Biology, Biotechnology, Infectious Diseases, Computational Biology, Space Science, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, mild reaction conditions, mechanistic studies revealed, broad substrate scope, oxyallyl cations generated, tfe )- promoted, oxyallyl cations, trifluoroethanol promoted, tosyloxy ketones, one derivatives, new applications, n <, including direct, excellent yields

Relation: https://figshare.com/articles/journal_contribution/Synthesis_of_Spirooxindole-1_2-oxazinan-5-ones_through_2_2_2-Trifluoroethanol_Promoted_3_3_Cycloaddition_of_i_N_i_Vinyl_Oxindole_Nitrones_and_Oxyallyl_Cations/24582510

الاتاحة: https://doi.org/10.1021/acs.joc.3c01477.s001
https://figshare.com/articles/journal_contribution/Synthesis_of_Spirooxindole-1_2-oxazinan-5-ones_through_2_2_2-Trifluoroethanol_Promoted_3_3_Cycloaddition_of_i_N_i_Vinyl_Oxindole_Nitrones_and_Oxyallyl_Cations/24582510

المؤلفون: Yadong Li, Dengfu Lu, Yuefa Gong

مصطلحات موضوعية: Biochemistry, Microbiology, Cell Biology, Genetics, Cancer, Inorganic Chemistry, Infectious Diseases, Computational Biology, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, various redox catalysts, thus successfully modified, mechanistic studies revealed, electrophilic trifluoromethylating reagent, >‑ aryl glycinates, radical addition cascade, oxyalkyl radical intermediate, oxyalkyl radical, imine intermediate, selectivity could, related peptides, protected enols, proper counterion, preferentially oxidized, n <, component oxyalkylation, competing oxidation

Relation: https://figshare.com/articles/journal_contribution/Cobalt_II_-Catalyzed_Selective_Three-Component_Oxyalkylation_of_i_N_i_Aryl_Glycinates_A_Route_to_CF_sub_3_sub_Labeled_Threonine_Analogues/24703450

الاتاحة: https://doi.org/10.1021/acs.joc.3c01874.s001
https://figshare.com/articles/journal_contribution/Cobalt_II_-Catalyzed_Selective_Three-Component_Oxyalkylation_of_i_N_i_Aryl_Glycinates_A_Route_to_CF_sub_3_sub_Labeled_Threonine_Analogues/24703450